Oxidation Reactions Performed by Soluble Methane Monooxygenase Hydroxylase Intermediates H[subscript peroxo] and Q Proceed by Distinct Mechanisms
Soluble methane monooxygenase is a bacterial enzyme that converts methane to methanol at a carboxylate-bridged diiron center with exquisite control. Because the oxidizing power required for this transformation is demanding, it is not surprising that the enzyme is also capable of hydroxylating and ep...
Main Authors: | Tinberg, Christine E. (Contributor), Lippard, Stephen J. (Contributor) |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry (Contributor) |
Format: | Article |
Language: | English |
Published: |
American Chemical Society,
2011-12-14T21:36:05Z.
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Subjects: | |
Online Access: | Get fulltext |
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