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|a Tonzetich, Zachary J.
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|a Massachusetts Institute of Technology. Department of Chemistry
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|a Lippard, Stephen J.
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|a Lippard, Stephen J.
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|a Tonzetich, Zachary J.
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|a Heroguel, Florent
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|a Do, Loi Hung
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|a Heroguel, Florent
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|a Do, Loi Hung
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|a Lippard, Stephen J.
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|a Chemistry of Nitrosyliron Complexes Supported by a beta-Diketiminate Ligand
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|a Chemistry of Nitrosyliron Complexes Supported by a β-Diketiminate Ligand
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|b American Chemical Society,
|c 2012-02-10T15:47:17Z.
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|z Get fulltext
|u http://hdl.handle.net/1721.1/69074
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|a Several nitrosyl complexes of Fe and Co have been prepared using the sterically hindered Ar-nacnac ligand (Ar-nacnac = anion of [(2,6-diisopropylphenyl)NC(Me)]2CH). The dinitrosyliron complexes [Fe(NO)2(Ar-nacnac)] (1) and (Bu4N)[Fe(NO)2(Ar-nacnac)] (2) react with [FeIII(TPP)Cl] (TPP = tetraphenylporphine dianion) to generate [FeII(NO)(TPP)] and the corresponding mononitrosyliron complexes. The factors governing NO transfer with dinitrosyliron complexes (DNICs) 1 and 2 are evaluated, together with the chemistry of the related mononitrosyliron complex, [Fe(NO)Br(Ar-nacnac)] (4). The synthesis and properties of the related cobalt dinitrosyl [Co(NO)2(Ar-nacnac)] (3) is also discussed for comparison to DNICs 1 and 2. The solid-state structures of several of these compounds as determined by X-ray crystallography are reported.
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|a National Science Foundation (U.S.) (grant CHE-0907905)
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|a National Institute of General Medical Sciences (U.S.) (postdoctoral fellowship, F32 GM082031-03)
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|a en_US
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|a Article
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|t Inorganic Chemistry
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