Reversible mechanism for spin crossover in transition-metal cyanides
We report the mechanisms for reversible and repeatable spin transition in a Prussian blue analog crystal, KCo[Fe(CN)[subscript 6]], derived from first-principles calculations. The forward and reverse transitions are initiated by metal-to-metal charge transfer, followed by the d-electron rearrangemen...
| Main Authors: | , |
|---|---|
| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
American Physical Society,
2012-07-24T20:10:18Z.
|
| Subjects: | |
| Online Access: | Get fulltext |