Reversible mechanism for spin crossover in transition-metal cyanides
We report the mechanisms for reversible and repeatable spin transition in a Prussian blue analog crystal, KCo[Fe(CN)[subscript 6]], derived from first-principles calculations. The forward and reverse transitions are initiated by metal-to-metal charge transfer, followed by the d-electron rearrangemen...
Main Authors: | Kabir, Mohammad Mukul (Contributor), Van Vliet, Krystyn J. (Contributor) |
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Other Authors: | Massachusetts Institute of Technology. Department of Materials Science and Engineering (Contributor) |
Format: | Article |
Language: | English |
Published: |
American Physical Society,
2012-07-24T20:10:18Z.
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Subjects: | |
Online Access: | Get fulltext |
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