A Multi-Ligand Based Pd Catalyst for C-N Cross-Coupling Reactions

An alternative approach to catalyst development, which led to a Pd catalyst based on two biarylphosphine ligands for C−N cross-coupling reactions, is reported. By effectively being able to take the form of multiple catalysts this system manifests the best properties that catalysts based on either of...

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Bibliographic Details
Main Authors: Fors, Brett P. (Contributor), Buchwald, Stephen Leffler (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor), Buchwald, Stephen L. (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2012-08-01T20:18:58Z.
Subjects:
Online Access:Get fulltext
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100 1 0 |a Fors, Brett P.  |e author 
100 1 0 |a Massachusetts Institute of Technology. Department of Chemistry  |e contributor 
100 1 0 |a Buchwald, Stephen L.  |e contributor 
100 1 0 |a Fors, Brett P.  |e contributor 
100 1 0 |a Buchwald, Stephen Leffler  |e contributor 
700 1 0 |a Buchwald, Stephen Leffler  |e author 
245 0 0 |a A Multi-Ligand Based Pd Catalyst for C-N Cross-Coupling Reactions 
260 |b American Chemical Society (ACS),   |c 2012-08-01T20:18:58Z. 
856 |z Get fulltext  |u http://hdl.handle.net/1721.1/71951 
520 |a An alternative approach to catalyst development, which led to a Pd catalyst based on two biarylphosphine ligands for C−N cross-coupling reactions, is reported. By effectively being able to take the form of multiple catalysts this system manifests the best properties that catalysts based on either of the two ligands exhibit separately and displays the highest reactivity and substrate scope of any system that has been reported to date for these reactions. 
520 |a National Institutes of Health (U.S.) (Grant Number GM58160) 
520 |a Amgen, Inc. Graduate Fellowship 
520 |a Boehringer Ingelheim Pharmaceuticals. Graduate Fellowship 
520 |a American Chemical Society. Graduate Fellowship 
546 |a en_US 
655 7 |a Article 
773 |t Journal of the American Chemical Society