General Approach to Epipolythiodiketopiperazine Alkaloids: Total Synthesis of (+)-Chaetocins A, C and (+)-12,12'- Dideoxychetracin A
A highly stereoselective and systematic strategy for the introduction of polysulfides in the synthesis of epipolythiodiketopiperazines is described. We report the first total synthesis of dimeric epitri- and epitetrathiodiketopiperazines.
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| Format: | Article |
| Language: | English |
| Published: |
American Chemical Society,
2012-09-24T19:31:16Z.
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| Subjects: | |
| Online Access: | Get fulltext |