Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies

The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold enforces proximity of the alcohol and arene reacting partners and confers significa...

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Bibliographic Details
Main Authors: VanVeller, Brett (Author), Swager, Timothy Manning (Contributor), Schipper, Derek James (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor), Swager, Timothy M. (Contributor), Vanveller, Brett (Contributor)
Format: Article
Language:English
Published: American Chemical Society, 2013-04-04T17:32:24Z.
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Online Access:Get fulltext
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042 |a dc 
100 1 0 |a VanVeller, Brett  |e author 
100 1 0 |a Massachusetts Institute of Technology. Department of Chemistry  |e contributor 
100 1 0 |a Swager, Timothy M.  |e contributor 
100 1 0 |a Schipper, Derek James  |e contributor 
100 1 0 |a Vanveller, Brett  |e contributor 
100 1 0 |a Swager, Timothy Manning  |e contributor 
700 1 0 |a Swager, Timothy Manning  |e author 
700 1 0 |a Schipper, Derek James  |e author 
245 0 0 |a Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies 
260 |b American Chemical Society,   |c 2013-04-04T17:32:24Z. 
856 |z Get fulltext  |u http://hdl.handle.net/1721.1/78290 
520 |a The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold enforces proximity of the alcohol and arene reacting partners and confers significant rigidity to the resulting π-system, expanding the tool set of iptycenes for materials applications. 
520 |a Natural Sciences and Engineering Research Council of Canada 
520 |a National Institutes of Health (U.S.) (NIH BRP grant R01 AG026240-01A1) 
520 |a Natural Sciences and Engineering Research Council of Canada (NSERC) (Postdoctoral Fellowship) 
520 |a United States. Air Force Office of Scientific Research (FA9550-10-1- 0395) 
546 |a en_US 
655 7 |a Article 
773 |t Journal of the American Chemical Society