Thiophene-based covalent organic frameworks

We report the synthesis and characterization of covalent organic frameworks (COFs) incorporating thiophene-based building blocks. We show that these are amenable to reticular synthesis, and that bent ditopic monomers, such as 2,5-thiophenediboronic acid, are defect-prone building blocks that are sus...

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Bibliographic Details
Main Authors: Bertrand, Guillaume (Contributor), Michaelis, Vladimir K. (Contributor), Ong, Ta-Chung (Contributor), Griffin, Robert Guy (Contributor), Dinca, Mircea (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor), Francis Bitter Magnet Laboratory (Massachusetts Institute of Technology) (Contributor)
Format: Article
Language:English
Published: National Academy of Sciences (U.S.), 2013-10-03T17:12:50Z.
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