Rhodium-Catalyzed Asymmetric Intramolecular Hydroamination of Unactivated Alkenes
One for the Rh(oad): The first rhodium-catalyzed asymmetric intramolecular hydroamination of unactivated olefins was developed by using dialkylbiaryl phosphine ligands (see scheme; cod=1,5-cyclooctadiene, Cy=cyclohexyl). A variety of 2-methylpyrrolidines have been synthesized with high enantioselect...
Main Authors: | Shen, Xiaoqiang (Contributor), Buchwald, Stephen Leffler (Contributor) |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry (Contributor) |
Format: | Article |
Language: | English |
Published: |
Wiley Blackwell,
2013-11-01T15:04:16Z.
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Subjects: | |
Online Access: | Get fulltext |
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