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01389 am a22002413u 4500 |
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82101 |
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|a Fors, Brett P.
|e author
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|a Massachusetts Institute of Technology. Department of Chemistry
|e contributor
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|a Buchwald, Stephen Leffler
|e contributor
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|a Fors, Brett P.
|e contributor
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|a Buchwald, Stephen Leffler
|e author
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|a Pd-Catalyzed Conversion of Aryl Chlorides, Triflates, and Nonaflates to Nitroaromatics
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|b American Chemical Society (ACS),
|c 2013-11-13T15:50:32Z.
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|z Get fulltext
|u http://hdl.handle.net/1721.1/82101
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|a An efficient Pd catalyst for the transformation of aryl chlorides, triflates, and nonaflates to nitroaromatics has been developed. This reaction proceeds under weakly basic conditions and displays a broad scope and excellent functional group compatibility. Moreover, this method allows for the synthesis of aromatic nitro compounds that cannot be accessed efficiently via other nitration protocols. Mechanistic insight into the transmetalation step of the catalytic process is also reported.
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|a National Institutes of Health (U.S.) (GM-58160)
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|a BASF
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|a Merck & Co. (Fellowship)
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|a William Asbornsen Albert Memorial Fund (Fellowship)
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|a en_US
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|a Article
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|t Journal of the American Chemical Society
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