Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes

A rhodium-catalyzed dehydrogenative borylation of cyclic alkenes is described. This reaction provides direct access to cyclic 1-alkenylboronic acid pinacol esters, useful intermediates in organic synthesis. Suzuki-Miyaura cross-coupling applications are also presented.

Bibliographic Details
Main Authors: Kondoh, Azusa (Contributor), Jamison, Timothy F. (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor)
Format: Article
Language:English
Published: Royal Society of Chemistry, 2013-11-15T17:00:47Z.
Subjects:
Online Access:Get fulltext
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100 1 0 |a Kondoh, Azusa  |e author 
100 1 0 |a Massachusetts Institute of Technology. Department of Chemistry  |e contributor 
100 1 0 |a Kondoh, Azusa  |e contributor 
100 1 0 |a Jamison, Timothy F.  |e contributor 
700 1 0 |a Jamison, Timothy F.  |e author 
245 0 0 |a Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes 
260 |b Royal Society of Chemistry,   |c 2013-11-15T17:00:47Z. 
856 |z Get fulltext  |u http://hdl.handle.net/1721.1/82127 
520 |a A rhodium-catalyzed dehydrogenative borylation of cyclic alkenes is described. This reaction provides direct access to cyclic 1-alkenylboronic acid pinacol esters, useful intermediates in organic synthesis. Suzuki-Miyaura cross-coupling applications are also presented. 
520 |a National Institute of General Medical Sciences (U.S.) (GM-63755) 
546 |a en_US 
655 7 |a Article 
773 |t Chemical Communications