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82153 |
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|a Li, Yang
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|a Massachusetts Institute of Technology. Department of Chemistry
|e contributor
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|a Li, Yang
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|a Cao, Rui
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|a Lippard, Stephen J.
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|a Cao, Rui
|e author
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|a Lippard, Stephen J.
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|a Design and Synthesis of a Novel Triptycene-Based Ligand for Modeling Carboxylate-Bridged Diiron Enzyme Active Sites
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|b American Chemical Society (ACS),
|c 2013-11-18T13:48:44Z.
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|z Get fulltext
|u http://hdl.handle.net/1721.1/82153
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|a A novel triptycene-based ligand with a preorganized framework was designed to model carboxylate-bridged diiron active sites in bacterial multicomponent monooxygenase (BMM) hydroxylase enzymes. The synthesis of the bis(benzoxazole)-appended ligand L1 depicted was accomplished in 11 steps. Reaction of L1 with iron(II) triflate and a carboxylate source afforded the desired diiron(II) complex [Fe[subscript 2]L1(μ-OH)(μ-O[subscript 2]CAr[superscript Tol])(OTf)[subscript 2]].
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|a National Institute of General Medical Sciences (U.S.) (Grant G032134)
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|a en_US
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|a Article
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|t Organic Letters
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