Five-Coordinate Rearrangements of Metallacyclobutane Intermediates During Ring-Opening Metathesis Polymerization (ROMP) of 2,3-Dicarboalkoxynorbornenes by Molybdenum and Tungsten Monoalkoxide Pyrrolide (MAP) Initiators
Addition of rac-DCENBE (2,3-dicarboethoxynorbornene) or rac-DCBNBE (2,3-dicarbo-tert-butoxynorbornene) to Mo(NAd)(CHCMe[subscript 2]Ph)(Pyr)(OHMT) (1a) (Ad = 1-adamantyl, OHMT = 2,6-dimesitylphenoxide, Pyr- = NC[subscript 4]H[subscript 4]-) led to the formation of polymers that have a cis,syndiotact...
Main Authors: | Flook, Margaret M. (Contributor), Kilyanek, Stefan M. (Contributor), Gerber, Laura C. H. (Contributor), Borner, Janna (Contributor), Schrock, Richard Royce (Contributor) |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry (Contributor) |
Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2014-01-21T17:25:57Z.
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Subjects: | |
Online Access: | Get fulltext |
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