Synthesis and Properties of the 5,10,15-Trimesityltruxen-5-yl Radical

Synthesis and Properties of the 5,10,15-Trimesityltruxen-5-yl Radical

The synthesis of a long-lived, truxene-based radical that is highly delocalized and exhibits a narrow EPR absorption is reported. The radical is stable for multiple hours in a solution exposed to air and remains for months in the solid state under inert gas. Characterization and properties are discu...

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Bibliographic Details
Main Authors: Frantz, Derik K. (Contributor), Walish, Joseph John (Contributor), Swager, Timothy Manning (Contributor)
Other Authors: Massachusetts Institute of Technology. Department of Chemistry (Contributor), Swager, Timothy M. (Contributor)
Format: Article
Language:English
Published: American Chemical Society (ACS), 2014-07-30T13:46:44Z.
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Summary:The synthesis of a long-lived, truxene-based radical that is highly delocalized and exhibits a narrow EPR absorption is reported. The radical is stable for multiple hours in a solution exposed to air and remains for months in the solid state under inert gas. Characterization and properties are discussed.
National Institutes of Health (U.S.) (GM095843)

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