Conversion between Doubly and Triply Carboxylate Bridged Bis(ethylzinc) Complexes and Formation of the (μ-Oxo)tetrazinc Carboxylate [Zn[subscript 4]O(Ar[superscript Tol]CO[subscript 2)[subscript 6]]
Ethylzinc 2,6-bis(p-tolyl)benzoate converts between two forms in solution. Through NMR spectroscopic techniques and X-ray crystallography, the species in equilibrium were identified as [Zn[subscript 2](Ar[superscript Tol]CO[subscript 2])[subscript 2](Et)[subscript 2](THF)[subscript 2]] (1), [Zn[subs...
Main Authors: | Lippard, Stephen J. (Contributor), Minier, Mikael Antoine (Contributor) |
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Other Authors: | Massachusetts Institute of Technology. Department of Chemistry (Contributor) |
Format: | Article |
Language: | English |
Published: |
American Chemical Society (ACS),
2015-03-03T15:19:40Z.
|
Subjects: | |
Online Access: | Get fulltext |
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