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01503 am a22002413u 4500 |
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97471 |
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|a Bruno, Nicholas C.
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|a Massachusetts Institute of Technology. Department of Chemistry
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|a Bruno, Nicholas C.
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|a Niljianskul, Nootaree
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|a Buchwald, Stephen Leffler
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|a Niljianskul, Nootaree
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|a Buchwald, Stephen Leffler
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|a N-Substituted 2-Aminobiphenylpalladium Methanesulfonate Precatalysts and Their Use in C-C and C-N Cross-Couplings
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|c 2015-06-19T14:57:15Z.
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|z Get fulltext
|u http://hdl.handle.net/1721.1/97471
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|a A series of phosphine-ligated palladium precatalysts based on N-methyl- and N-phenyl-2-aminobiphenyl have been developed. Substitution at the nitrogen center prevents the presence of traces of aminobiphenyls that contain a free −NH[subscript 2] group from contaminating cross-coupling products. These precatalysts produce N-substituted carbazoles upon activation, which cannot consume starting materials. These precatalysts were efficiently generated from 2-aminobiphenyl with minimal purification and found to be highly effective in Suzuki-Miyaura and C-N cross-coupling reactions.
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|a National Institutes of Health (U.S.) (GM46059)
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|a National Institutes of Health (U.S.) (GM58160)
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|a en_US
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|a Article
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|t The Journal of Organic Chemistry
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