I. Asymmetric Alkylation Reactions of Chiral Imide Enolates. II. Efforts Directed Toward the Total Synthesis of (+)-Macbecin I

I. Asymmetric Alkylation Reactions of Chiral Imide Enolates. II. Efforts Directed Toward the Total Synthesis of (+)-Macbecin I

<p>The preparation of chiral N-acyl oxazolidones 6 and 7 from readily available amino acid precursors is described. Reaction of the alkali metal enolates derived from these chiral imides with alkyl halides and acid chlorides exhibit high levels of kinetic diastereoselection. Chromatographic en...

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Bibliographic Details
Main Author: Ennis, Michael Dalton
Format: Others
Language:en
Published: 1983
Online Access:https://thesis.library.caltech.edu/11788/1/Ennis_MD_1983.pdf
Ennis, Michael Dalton (1983) I. Asymmetric Alkylation Reactions of Chiral Imide Enolates. II. Efforts Directed Toward the Total Synthesis of (+)-Macbecin I. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/pqm8-7286. https://resolver.caltech.edu/CaltechTHESIS:09032019-124939824 <https://resolver.caltech.edu/CaltechTHESIS:09032019-124939824>

Internet

https://thesis.library.caltech.edu/11788/1/Ennis_MD_1983.pdf
Ennis, Michael Dalton (1983) I. Asymmetric Alkylation Reactions of Chiral Imide Enolates. II. Efforts Directed Toward the Total Synthesis of (+)-Macbecin I. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/pqm8-7286. https://resolver.caltech.edu/CaltechTHESIS:09032019-124939824 <https://resolver.caltech.edu/CaltechTHESIS:09032019-124939824>

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