The photoreactions of N-methyl-2-pyridone
In studying the photochemistry of N-methyl-2- pyridone, four products were observed. Besides the previously known dimer and bicyclic monomer, two new dimers were isolated. The quantum yields of product formation were measured, and it was found that only one intermediate was involved. From sensitiza...
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ndltd-CALTECH-oai-thesis.library.caltech.edu-794 |
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ndltd-CALTECH-oai-thesis.library.caltech.edu-7942019-12-22T03:06:07Z The photoreactions of N-methyl-2-pyridone Sharp, Louis James In studying the photochemistry of N-methyl-2- pyridone, four products were observed. Besides the previously known dimer and bicyclic monomer, two new dimers were isolated. The quantum yields of product formation were measured, and it was found that only one intermediate was involved. From sensitization and quenching experiments, the lowest excited singlet state appears to be that intermediate although a highly reactive, ground state isomer cannot be ruled out. Some spectroscopic evidence for this isomer is given. 1970 Thesis NonPeerReviewed application/pdf https://thesis.library.caltech.edu/794/1/Sharp_lj_1970.pdf https://resolver.caltech.edu/CaltechETD:etd-02272009-095718 Sharp, Louis James (1970) The photoreactions of N-methyl-2-pyridone. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/RK5J-7E32. https://resolver.caltech.edu/CaltechETD:etd-02272009-095718 <https://resolver.caltech.edu/CaltechETD:etd-02272009-095718> https://thesis.library.caltech.edu/794/ |
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In studying the photochemistry of N-methyl-2- pyridone, four products were observed. Besides the previously known dimer and bicyclic monomer, two new dimers were isolated.
The quantum yields of product formation were measured, and it was found that only one intermediate was involved. From sensitization and quenching experiments, the lowest excited singlet state appears to be that intermediate although a highly reactive, ground state isomer cannot be ruled out. Some spectroscopic evidence for this isomer is given.
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| author |
Sharp, Louis James |
| spellingShingle |
Sharp, Louis James The photoreactions of N-methyl-2-pyridone |
| author_facet |
Sharp, Louis James |
| author_sort |
Sharp, Louis James |
| title |
The photoreactions of N-methyl-2-pyridone |
| title_short |
The photoreactions of N-methyl-2-pyridone |
| title_full |
The photoreactions of N-methyl-2-pyridone |
| title_fullStr |
The photoreactions of N-methyl-2-pyridone |
| title_full_unstemmed |
The photoreactions of N-methyl-2-pyridone |
| title_sort |
photoreactions of n-methyl-2-pyridone |
| publishDate |
1970 |
| url |
https://thesis.library.caltech.edu/794/1/Sharp_lj_1970.pdf Sharp, Louis James (1970) The photoreactions of N-methyl-2-pyridone. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/RK5J-7E32. https://resolver.caltech.edu/CaltechETD:etd-02272009-095718 <https://resolver.caltech.edu/CaltechETD:etd-02272009-095718> |
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AT sharplouisjames thephotoreactionsofnmethyl2pyridone AT sharplouisjames photoreactionsofnmethyl2pyridone |
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