The Development of a Synthetic Strategy Toward Dihydrooxepine-Containing Epipolythiodiketopiperazines: Enantioselective Total Synthesis of (-)-Acetylaranotin and Related Investigations
<p>To the chemist, the epipolythiodiketopiperazine (ETP) fungal metabolites represent a fascinating family of natural products, not only for their unique structural elements, but also for the unusual modes by which they are hypothesized to exert their biological activities. Though efforts at t...