Mild Preparation of Anode Materials for Lithim Ion Batteries: from Gas-Phase Oxidation to Salt-free Green Method

• Main Authors: Holze, Rudolf, Wu, Yuping
• Other Authors: TU Chemnitz, Fakultät für Naturwissenschaften
• Format: Article
• Language: English
• Published: Universitätsbibliothek Chemnitz 2009
• Subjects: Anode material; Lithium ion battery; Mild oxidation; Natural graphite; ddc:540; Elektrochemie; Graphit; Lithium
• Online Access: http://nbn-resolving.de/urn:nbn:de:bsz:ch1-200901922; http://nbn-resolving.de/urn:nbn:de:bsz:ch1-200901922; http://www.qucosa.de/fileadmin/data/qucosa/documents/5913/data/wuho23f.pdf; http://www.qucosa.de/fileadmin/data/qucosa/documents/5913/20090192.txt

Natural graphite from cheap and abundant natural sources is an attractive anode material for lithium ion batteries. We report on modifications of such a common natural graphite, whose electrochemical performance is very poor, with solutions of (NH4)2S2O8, concentrated nitric acid, and green chemical solutions such of e.g. hydrogen peroxide and ceric sulfate. These treatments resulted in markedly im-proved electrochemical performance (reversible capacity, coulombic efficiency in the first cycle and cycling behavior). This is attributed to the effective removal of active defects, formation of a new dense surface film consisting of oxides, improvement of the graphite stability, and introduction of more nanochannels/micropores. These changes inhibit the decomposition of electrolyte solution, pre-vent the movement of graphene planes along a-axis direction, and provide more passage and storage sites for lithium. The methods are mild, and the uniformity of the product can be well controlled. Pilot experiments show promising results for their application in industry.