Crystal structure of ruthenocenecarbonitrile
The molecular structure of ruthenocenecarbonitrile, [Ru([eta]5-C5H4C[triple bond]N)([eta]5-C5H5)], exhibits point group symmetry m, with the mirror plane bisecting the molecule through the C[triple bond]N substituent. The RuII atom is slightly shifted from the [eta]5-C5H4 centroid towards the C[...
Main Authors: | , , |
---|---|
Other Authors: | |
Format: | Article |
Language: | English |
Published: |
Universitätsbibliothek Chemnitz
2015
|
Subjects: | |
Online Access: | http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-166700 http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-166700 http://www.qucosa.de/fileadmin/data/qucosa/documents/16670/wm5119.pdf http://www.qucosa.de/fileadmin/data/qucosa/documents/16670/signatur.txt.asc |
id |
ndltd-DRESDEN-oai-qucosa.de-bsz-ch1-qucosa-166700 |
---|---|
record_format |
oai_dc |
spelling |
ndltd-DRESDEN-oai-qucosa.de-bsz-ch1-qucosa-1667002016-11-13T03:32:12Z Crystal structure of ruthenocenecarbonitrile Strehler, Frank Korb, Marcus Lang, Heinrich Kristallstruktur Nitrile Technische Universität Chemnitz Publikationsfonds crystal structure ruthenocene ruthenocenecarbonitrile sandwich compound nitrile Technische Universität Chemnitz Publication funds ddc:546 Kristallstruktur Nitrile The molecular structure of ruthenocenecarbonitrile, [Ru([eta]5-C5H4C[triple bond]N)([eta]5-C5H5)], exhibits point group symmetry m, with the mirror plane bisecting the molecule through the C[triple bond]N substituent. The RuII atom is slightly shifted from the [eta]5-C5H4 centroid towards the C[triple bond]N substituent. In the crystal, molecules are arranged in columns parallel to [100]. One-dimensional intermolecular [pi]-[pi] interactions [3.363 (3) Å] between the C[triple bond]N carbon atom and one carbon of the cyclopentadienyl ring of the overlaying molecule are present. Universitätsbibliothek Chemnitz International Union of Crystallography IUCR, Technische Universität Chemnitz, Fakultät für Naturwissenschaften 2015-05-07 doc-type:article application/pdf text/plain application/zip http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-166700 urn:nbn:de:bsz:ch1-qucosa-166700 issn:1600-5368 / 2056-9890 http://www.qucosa.de/fileadmin/data/qucosa/documents/16670/wm5119.pdf http://www.qucosa.de/fileadmin/data/qucosa/documents/16670/signatur.txt.asc Acta Cryst. (2015). E71, 398-401 eng |
collection |
NDLTD |
language |
English |
format |
Article |
sources |
NDLTD |
topic |
Kristallstruktur Nitrile Technische Universität Chemnitz Publikationsfonds crystal structure ruthenocene ruthenocenecarbonitrile sandwich compound nitrile Technische Universität Chemnitz Publication funds ddc:546 Kristallstruktur Nitrile |
spellingShingle |
Kristallstruktur Nitrile Technische Universität Chemnitz Publikationsfonds crystal structure ruthenocene ruthenocenecarbonitrile sandwich compound nitrile Technische Universität Chemnitz Publication funds ddc:546 Kristallstruktur Nitrile Strehler, Frank Korb, Marcus Lang, Heinrich Crystal structure of ruthenocenecarbonitrile |
description |
The molecular structure of ruthenocenecarbonitrile, [Ru([eta]5-C5H4C[triple bond]N)([eta]5-C5H5)], exhibits point group symmetry m, with the mirror plane bisecting the molecule through the C[triple bond]N substituent. The RuII atom is slightly shifted from the [eta]5-C5H4 centroid towards the C[triple bond]N substituent. In the crystal, molecules are arranged in columns parallel to [100]. One-dimensional intermolecular [pi]-[pi] interactions [3.363 (3) Å] between the C[triple bond]N carbon atom and one carbon of the cyclopentadienyl ring of the overlaying molecule are present. |
author2 |
International Union of Crystallography IUCR, |
author_facet |
International Union of Crystallography IUCR, Strehler, Frank Korb, Marcus Lang, Heinrich |
author |
Strehler, Frank Korb, Marcus Lang, Heinrich |
author_sort |
Strehler, Frank |
title |
Crystal structure of ruthenocenecarbonitrile
|
title_short |
Crystal structure of ruthenocenecarbonitrile
|
title_full |
Crystal structure of ruthenocenecarbonitrile
|
title_fullStr |
Crystal structure of ruthenocenecarbonitrile
|
title_full_unstemmed |
Crystal structure of ruthenocenecarbonitrile
|
title_sort |
crystal structure of ruthenocenecarbonitrile |
publisher |
Universitätsbibliothek Chemnitz |
publishDate |
2015 |
url |
http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-166700 http://nbn-resolving.de/urn:nbn:de:bsz:ch1-qucosa-166700 http://www.qucosa.de/fileadmin/data/qucosa/documents/16670/wm5119.pdf http://www.qucosa.de/fileadmin/data/qucosa/documents/16670/signatur.txt.asc |
work_keys_str_mv |
AT strehlerfrank crystalstructureofruthenocenecarbonitrile AT korbmarcus crystalstructureofruthenocenecarbonitrile AT langheinrich crystalstructureofruthenocenecarbonitrile |
_version_ |
1718392321187250176 |