Coupling reactions and separations in propane-organic-aqueous tunable solvent systems
Developing environmentally sustainable processes are essential to improving the quality of life for future generations. In addition to reducing our impact on the environment, we must design processes to be both economical and safe. A large component of any chemical process is the solvents used to di...
Main Author: | |
---|---|
Published: |
Georgia Institute of Technology
2009
|
Subjects: | |
Online Access: | http://hdl.handle.net/1853/29719 |
id |
ndltd-GATECH-oai-smartech.gatech.edu-1853-29719 |
---|---|
record_format |
oai_dc |
spelling |
ndltd-GATECH-oai-smartech.gatech.edu-1853-297192013-01-07T20:33:01ZCoupling reactions and separations in propane-organic-aqueous tunable solvent systemsHusain, Zainul AbideenPropanePhase equilibriaTunable solventsSolventsChemical reactionsTetrahydrofuranAcetoneDeveloping environmentally sustainable processes are essential to improving the quality of life for future generations. In addition to reducing our impact on the environment, we must design processes to be both economical and safe. A large component of any chemical process is the solvents used to dissolve the reactants and extract the products. The research presented here focuses on coupling efficient homogeneous reactions with simple heterogeneous separations using propane-organic-aqueous tunable solvent systems. Our tunable solvents undergo a phase separation upon application of propane pressure to a fully miscible mixture of water and an organic solvent. The propane based tunable systems detailed here eliminate carbonic acid formation and reduce productphase contamination when compared with the equivalent CO2 based solvent systems previously studied. Additionally, we eliminate the need to use buffers and thus solids handling equipment is not needed.Georgia Institute of Technology2009-08-26T17:50:36Z2009-08-26T17:50:36Z2009-06-29Thesishttp://hdl.handle.net/1853/29719 |
collection |
NDLTD |
sources |
NDLTD |
topic |
Propane Phase equilibria Tunable solvents Solvents Chemical reactions Tetrahydrofuran Acetone |
spellingShingle |
Propane Phase equilibria Tunable solvents Solvents Chemical reactions Tetrahydrofuran Acetone Husain, Zainul Abideen Coupling reactions and separations in propane-organic-aqueous tunable solvent systems |
description |
Developing environmentally sustainable processes are essential to improving the quality
of life for future generations. In addition to reducing our impact on the environment, we
must design processes to be both economical and safe. A large component of any
chemical process is the solvents used to dissolve the reactants and extract the products.
The research presented here focuses on coupling efficient homogeneous reactions with
simple heterogeneous separations using propane-organic-aqueous tunable solvent
systems. Our tunable solvents undergo a phase separation upon application of propane
pressure to a fully miscible mixture of water and an organic solvent. The propane based
tunable systems detailed here eliminate carbonic acid formation and reduce productphase
contamination when compared with the equivalent CO2 based solvent systems
previously studied. Additionally, we eliminate the need to use buffers and thus solids
handling equipment is not needed. |
author |
Husain, Zainul Abideen |
author_facet |
Husain, Zainul Abideen |
author_sort |
Husain, Zainul Abideen |
title |
Coupling reactions and separations in propane-organic-aqueous tunable solvent systems |
title_short |
Coupling reactions and separations in propane-organic-aqueous tunable solvent systems |
title_full |
Coupling reactions and separations in propane-organic-aqueous tunable solvent systems |
title_fullStr |
Coupling reactions and separations in propane-organic-aqueous tunable solvent systems |
title_full_unstemmed |
Coupling reactions and separations in propane-organic-aqueous tunable solvent systems |
title_sort |
coupling reactions and separations in propane-organic-aqueous tunable solvent systems |
publisher |
Georgia Institute of Technology |
publishDate |
2009 |
url |
http://hdl.handle.net/1853/29719 |
work_keys_str_mv |
AT husainzainulabideen couplingreactionsandseparationsinpropaneorganicaqueoustunablesolventsystems |
_version_ |
1716475156581318656 |