Inibi??o ? corros?o do a?o AISI 1020, em meios ?cido e salino, por tensoativos e subst?ncias nitrogenadas microemulsionados

• Main Author: Rossi, C?tia Guaraciara Fernandes Teixeira
• Other Authors: CPF:37320165449
• Format: Others
• Language: Portuguese
• Published: Universidade Federal do Rio Grande do Norte 2014
• Subjects: A?o Carbono AISI 1020; Tensoativos; Sistemas Microemulsionados; Subst?ncias Nitrogenadas; Inibidores de Corros?o; AISI 1020 Carbon steel; Surfactants; Microemulsion System; Nitrogenated Substances; Corrosion inhibitors; CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA
• Online Access: http://repositorio.ufrn.br:8080/jspui/handle/123456789/17668

Made available in DSpace on 2014-12-17T15:41:59Z (GMT). No. of bitstreams: 1 CatiaGFTR.pdf: 919760 bytes, checksum: a600b348289df4c6fa4bb6a54fb4e084 (MD5) Previous issue date: 2007-08-17 === Coordena??o de Aperfei?oamento de Pessoal de N?vel Superior === Corrosion inhibition efficiency of saponified coconut oil (SCO) and sodium dodecilbenzene sulfonate (DBS) surfactants in AISI 1020 carbon steel was evaluated by electrochemical methods. These surfactants were also evaluated as microemulsion systems (SCO-ME and DBS-ME), of O/W type (water-rich microemulsion), in a Winsor IV region. They were obtained according to the following composition: 15% SCO, 15% butanol (30% Co-surfactant/Surfactant C/T), 10% organic phase (FO, kerosene) and 60% aqueous phase (FA). These systems were also used to solubilize the following nitrogenated substances: Diphenylcarbazide (DC), 2,4-dinitro-phenyl-thiosemicarbazide (TSC) and the mesoionic type compound 1,3,4-triazolium-2-thiolate (MI), that were investigated with the purpose of evaluating their anticorrosive effects. Comparative studies of carbon steel corrosion inhibition efficiencies of free DBS and DBS-ME, in brine and acidic media (0.5%), showed that DBS presents better inhibition results in acidic media (free DBS, 89% and DBS-ME, 93%). However, the values obtained for DBS in salted solution (72% free DBS and 77% DBS-ME) were similar to the ones observed for the SCO surfactant in brine (63% free SCO and 74% SCO-ME). Analysis of corrosion inhibition of the nitrogenated substances that were solubilized in the SCO-ME microemulsion system by the linear polarization method in brine (0.5% NaCl) showed that such compounds are very efficient an corrosion inhibitors [DC-ME-SCO (92%), TSC-ME-SCO (93%) and MI-ME-SCO (94%)] === A efici?ncia de inibi??o ? corros?o em a?o AISI 1020 dos tensoativos ?leo de coco saponificado (OCS) e dodecilbenzeno sulfonato de s?dio (DBS), foi avaliada por m?todos eletroqu?micos. Estes tensoativos foram tamb?m avaliados em sistemas microemulsionados (OCS-ME e DBS-ME), do tipo O/A (microemuls?o rica em ?gua) com regi?o de trabalho Winsor IV, e foram obtidos na seguinte composi??o: 15% de OCS, 15% de butanol (30% de Cotensoativo/tensoativo - C/T), 10% de fase org?nica (FO, querosene) e 60% de fase aquosa (FA), tendo sido utilizados, ainda, para a solubiliza??o das subst?ncias nitrogenadas difenilcarbazida (DC), 2,4-dinitro-fenil-tiossemicarbazida (TSC) e do heterociclo do tipo mesoi?nico 1,3,4-triaz?lio-2-tiolato (MI), que foram disponibilizadas para avalia??o dos seus efeitos anticorrosivos. Os estudos comparativos das efici?ncias dos tensoativos DBS livre e DBS-ME na inibi??o da corros?o de a?o carbono, em meios salino e ?cido (0,5%), mostraram que o DBS apresenta melhores resultados de inibi??o em meio ?cido (DBS livre, 89% e DBS-ME, 93%). No entanto, os valores obtidos para o DBS em meio salino (72% DBS livre e 77% DBS-ME) foram semelhantes aos valores observados para o tensoativo OCS em meio salino (63% OCS livre e 74% OCS-ME). A an?lise de inibi??o ? corros?o das subst?ncias nitrogenadas solubilizadas no sistema microemulsionado OCS-ME, pelo m?todo de curvas de polariza??o linear em meio salino (NaCl 0,5%) mostrou que tais compostos s?o muito eficazes na inibi??o ? corros?o [DC-ME-OCS (92%), TSC-ME-OCS (93%) e MI-ME-OCS (94%)]