Recupera??o de fluido de perfura??o n?o aquoso utilizando sistemas microemulsionados

• Main Author: Alves, N?rio C?zar C?mara
• Other Authors: 05641284491
• Language: Portuguese
• Published: PROGRAMA DE P?S-GRADUA??O EM ENGENHARIA QU?MICA 2017
• Subjects: CNPQ::ENGENHARIAS::ENGENHARIA QUIMICA; Fluido de perfura??o; Microemuls?o; Recupera??o desemulsificantes tensoativos
• Online Access: https://repositorio.ufrn.br/jspui/handle/123456789/23698

Submitted by Automa??o e Estat?stica ([e-mail]) on 2017-08-01T13:13:46Z No. of bitstreams: 1 NarioCezarCamaraAlves_DISSERT.pdf: 3724020 bytes, checksum: 7d9bb0f760270e1cb1c18ea011288bb0 (MD5) === Approved for entry into archive by Arlan Eloi Leite Silva ([e-mail]) on 2017-08-03T23:20:45Z (GMT) No. of bitstreams: 1 NarioCezarCamaraAlves_DISSERT.pdf: 3724020 bytes, checksum: 7d9bb0f760270e1cb1c18ea011288bb0 (MD5) === Made available in DSpace on 2017-08-03T23:20:46Z (GMT). No. of bitstreams: 1 NarioCezarCamaraAlves_DISSERT.pdf: 3724020 bytes, checksum: 7d9bb0f760270e1cb1c18ea011288bb0 (MD5) Previous issue date: 2016-12-20 === Dois campos de pesquisas s?o essenciais para o mercado do petr?leo nos dias atuais: otimiza??o de custos e quest?es ambientais. Nas opera??es de perfura??o de po?os o sistema de fluido se mostra como sendo essencial, e assim requer uma otimiza??o cont?nua. Fluidos de perfura??o ? base org?nica s?o largamente utilizados nestas opera??es, onde, ap?s a sua utiliza??o, se tornam um passivo caro e poluente. Atualmente o tratamento realizado neste tipo de fluido ? somente de corre??o, o que requer, geralmente, grandes quantidades de insumos, elevando ainda mais o custo do Sistema de Fluidos para a opera??o de perfura??o. Com isso, o objetivo deste trabalho foi desenvolver um m?todo de recupera??o de fluidos de perfura??o n?o aquosos atrav?s da quebra da emuls?o de ?gua em ?leo, utilizando como agente desemulsificante sistemas microemulsionados. Para a obten??o desta microemuls?o estudou-se qualitativamente a influ?ncia de diferentes tensoativos na separa??o de fases do fluido e definiu-se o de melhor efici?ncia (ULX 95). Para mapeamento do fluido utilizado nos ensaios foram feitas an?lises de reologia, raz?o de ?gua/?leo/s?lidos, salinidade e Estabilidade El?trica. Para o estudo da quebra de emuls?o variou-se: a composi??o do sistema microemulsionado para o tensoativo ULX 95, a fase aquosa da microemuls?o atrav?s da utiliza??o ou n?o de sal (CaCl2), a propor??o sistema microemulsionado/fluido e a temperatura no momento da mistura. Tamb?m foram feitos testes para a caracteriza??o das fases obtidas ap?s o ensaio de quebra, assim como a possibilidade de reutiliza??o do fluido n?o-aquoso recuperado. Os testes de reutiliza??o do fluido n?o aquoso recuperado obtiveram resultados satisfat?rios. === There are two research fields essential for the oil market: cost optimization and environmental issues. In the well drilling operations the fluid system is shown to be essential, and thus requires a continuous optimization. Organic based drilling fluids are widely used in these operations, which, after use, become expensive and polluting liabilities. Currently the treatment performed in this type of fluid is only correction, which usually requires large quantities of inputs, further increasing the cost of Fluid System for the drilling operation. Thus, the aim of this study was to develop a method of recovery of non-aqueous drilling fluids through the breaking of the water in oil emulsion using as demulsifying agent microemulsions systems. To obtain the microemulsion system qualitative studies were performed where the influence of different surfactants in the phase separation of the fluid were studied and defined the best efficiency (RNX 95). For mapping of the fluid used in the tests were made rheology analysis, ratio of water / oil / solids, salinity, and electrical stability to study the emulsion breaking was varied: the composition of microemulsion system for the surfactant (RNX 95), the aqueous phase of the microemulsion by using or not salt (CaCl2), the rate microemulsion / fluid system and the temperature at mixture. Test have also been made to the characterization of phases obtained after breaking test, as well as the possibility of reusing the non-aqueous fluid recovered. The tests had a satisfactory result.