5-N,C-Disubstituted cyclopentadienes for facially selective Diels-Alder reactions

5-N,C-Disubstituted cyclopentadienes for facially selective Diels-Alder reactions

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This thesis describes research on the Diels-Alder facial selectivities of 5-N,C-disubstituted cyclopentadienes. Two novel chiral cyclopentadienes were created, both display facial selectivity in Diels-Alder reactions. Moreover, the two cyclopentadienes display opposing facial selectivities, and thus...

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Main Author: Kim, Simon J.
Language:English
Published: University of British Columbia 2010
Online Access:http://hdl.handle.net/2429/30061
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spelling ndltd-LACETR-oai-collectionscanada.gc.ca-BVAU.2429-300612014-03-26T03:37:28Z 5-N,C-Disubstituted cyclopentadienes for facially selective Diels-Alder reactions Kim, Simon J. This thesis describes research on the Diels-Alder facial selectivities of 5-N,C-disubstituted cyclopentadienes. Two novel chiral cyclopentadienes were created, both display facial selectivity in Diels-Alder reactions. Moreover, the two cyclopentadienes display opposing facial selectivities, and thus allow tunable control of faciality. The results obtained in the course of these studies have important implications for ongoing synthetic efforts in our laboratory. 2010-11-22T15:40:05Z 2010-11-22T15:40:05Z 2010 2010-11-22T15:40:05Z 2011-05 Electronic Thesis or Dissertation http://hdl.handle.net/2429/30061 eng University of British Columbia
collection NDLTD
language English
sources NDLTD
description This thesis describes research on the Diels-Alder facial selectivities of 5-N,C-disubstituted cyclopentadienes. Two novel chiral cyclopentadienes were created, both display facial selectivity in Diels-Alder reactions. Moreover, the two cyclopentadienes display opposing facial selectivities, and thus allow tunable control of faciality. The results obtained in the course of these studies have important implications for ongoing synthetic efforts in our laboratory.
author Kim, Simon J.
spellingShingle Kim, Simon J.
5-N,C-Disubstituted cyclopentadienes for facially selective Diels-Alder reactions
author_facet Kim, Simon J.
author_sort Kim, Simon J.
title 5-N,C-Disubstituted cyclopentadienes for facially selective Diels-Alder reactions
title_short 5-N,C-Disubstituted cyclopentadienes for facially selective Diels-Alder reactions
title_full 5-N,C-Disubstituted cyclopentadienes for facially selective Diels-Alder reactions
title_fullStr 5-N,C-Disubstituted cyclopentadienes for facially selective Diels-Alder reactions
title_full_unstemmed 5-N,C-Disubstituted cyclopentadienes for facially selective Diels-Alder reactions
title_sort 5-n,c-disubstituted cyclopentadienes for facially selective diels-alder reactions
publisher University of British Columbia
publishDate 2010
url http://hdl.handle.net/2429/30061
work_keys_str_mv AT kimsimonj 5ncdisubstitutedcyclopentadienesforfaciallyselectivedielsalderreactions
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