Molecular Shape Amphiphile Based on Keggin Polyoxometalates and iso-Butyl Polyhedral Oligomeric Silsesquioxanes: Synthesis and Characterization

Molecular Shape Amphiphile Based on Keggin Polyoxometalates and iso-Butyl Polyhedral Oligomeric Silsesquioxanes: Synthesis and Characterization

Bibliographic Details
Main Author: Shan, Wenpeng
Language:English
Published: University of Akron / OhioLINK 2014
Subjects:
Polymers
Polymer Chemistry
Polyoxometalates
Polyhedral Oligomeric Silsesquioxanes
Nano-particles
Online Access:http://rave.ohiolink.edu/etdc/view?acc_num=akron1405345461
id ndltd-OhioLink-oai-etd.ohiolink.edu-akron1405345461
record_format oai_dc
spelling ndltd-OhioLink-oai-etd.ohiolink.edu-akron14053454612021-08-03T06:26:00Z Molecular Shape Amphiphile Based on Keggin Polyoxometalates and iso-Butyl Polyhedral Oligomeric Silsesquioxanes: Synthesis and Characterization Shan, Wenpeng Polymers Polymer Chemistry Polyoxometalates Polyhedral Oligomeric Silsesquioxanes Nano-particles The controlled assembly of large nano-molecular clusters is a great challenge since the reliable assembly of new architectures is significantly important for not only exploring the fundamentals of structures but also extending the range of new materials, properties and devices. It suggests that the reliable organic and inorganic synthesis of gigantic molecules may define a new age in nano-science. In our group, we utilize Polyhedral Oligomeric Silsesquioxanes (POSS) and Polyoxometalates (POMs) to construct the giant molecules. On one hand, POSS are of conformational rigidity with the approximate size of 1 nm, which possess a good thermal stability and versatile surface chemical functionalities. On the other hand, POMs are the discrete metal-oxygen (also some hetero-atoms) anionic clusters that are formed by some early-transition metals (e.g. Vanadium (V), Molybdenum (Mo), tungsten (W)) in their high oxidation state. The surface charge property of POM clusters is quite so intriguing for researchers that a large library of POMs-based hybrid materials could be imagined. In my project, POMs and POSS connected by a series of covalent bonds are carried out to study its structure both in bulk and thin film. 2014-09-17 English text University of Akron / OhioLINK http://rave.ohiolink.edu/etdc/view?acc_num=akron1405345461 http://rave.ohiolink.edu/etdc/view?acc_num=akron1405345461 unrestricted This thesis or dissertation is protected by copyright: all rights reserved. It may not be copied or redistributed beyond the terms of applicable copyright laws.
collection NDLTD
language English
sources NDLTD
topic Polymers
Polymer Chemistry
Polyoxometalates
Polyhedral Oligomeric Silsesquioxanes
Nano-particles
spellingShingle Polymers
Polymer Chemistry
Polyoxometalates
Polyhedral Oligomeric Silsesquioxanes
Nano-particles
Shan, Wenpeng
Molecular Shape Amphiphile Based on Keggin Polyoxometalates and iso-Butyl Polyhedral Oligomeric Silsesquioxanes: Synthesis and Characterization
author Shan, Wenpeng
author_facet Shan, Wenpeng
author_sort Shan, Wenpeng
title Molecular Shape Amphiphile Based on Keggin Polyoxometalates and iso-Butyl Polyhedral Oligomeric Silsesquioxanes: Synthesis and Characterization
title_short Molecular Shape Amphiphile Based on Keggin Polyoxometalates and iso-Butyl Polyhedral Oligomeric Silsesquioxanes: Synthesis and Characterization
title_full Molecular Shape Amphiphile Based on Keggin Polyoxometalates and iso-Butyl Polyhedral Oligomeric Silsesquioxanes: Synthesis and Characterization
title_fullStr Molecular Shape Amphiphile Based on Keggin Polyoxometalates and iso-Butyl Polyhedral Oligomeric Silsesquioxanes: Synthesis and Characterization
title_full_unstemmed Molecular Shape Amphiphile Based on Keggin Polyoxometalates and iso-Butyl Polyhedral Oligomeric Silsesquioxanes: Synthesis and Characterization
title_sort molecular shape amphiphile based on keggin polyoxometalates and iso-butyl polyhedral oligomeric silsesquioxanes: synthesis and characterization
publisher University of Akron / OhioLINK
publishDate 2014
url http://rave.ohiolink.edu/etdc/view?acc_num=akron1405345461
work_keys_str_mv AT shanwenpeng molecularshapeamphiphilebasedonkegginpolyoxometalatesandisobutylpolyhedraloligomericsilsesquioxanessynthesisandcharacterization
_version_ 1719436651032215552

Similar Items