A pentacycloundecadione ring fused cyclohexadiene: Synthesis,. pi.-facial selectivity in the Diels-Alder cyclo- addition and base-promoted rearrangements

碩士 === 東海大學 === 應用化學系 === 81 === 15,15 - 二甲基-1,12,13,14-四氯六環 [10.2.1.0(2,11) .0(4,9) (4,14) .0(9,13)]十五烷-5,7-二烯-3,10-二酮46的合成 , 係利用 3,4-四氯-5,5-二甲氧環戊二烯與1,4奈錕反應做狄爾斯-亞德環化加成產物37 , 將化合物37照光得籠狀化合物31. 31 順丁烯二酐 ,2對苯錕 ,1,4奈錕做狄爾斯-亞德反應得...

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Main Authors:	Wu,Y.F., 吳炎豐
Other Authors:	Chou,D.T.
Format:	Others
Language:	zh-TW
Published:	1993
Online Access:	http://ndltd.ncl.edu.tw/handle/92946707589176539880

id	ndltd-TW-081THU00500007
record_format	oai_dc
spelling	ndltd-TW-081THU005000072016-02-10T04:08:48Z http://ndltd.ncl.edu.tw/handle/92946707589176539880 A pentacycloundecadione ring fused cyclohexadiene: Synthesis,. pi.-facial selectivity in the Diels-Alder cyclo- addition and base-promoted rearrangements 五環十一烯二酮稠和的環己二烯:合成,狄爾斯-亞德環化加成的.pi.面選擇和鹼促化重排反應 Wu,Y.F. 吳炎豐碩士東海大學應用化學系 81 15,15 - 二甲基-1,12,13,14-四氯六環 [10.2.1.0(2,11) .0(4,9) (4,14) .0(9,13)]十五烷-5,7-二烯-3,10-二酮46的合成 , 係利用 3,4-四氯-5,5-二甲氧環戊二烯與1,4奈錕反應做狄爾斯-亞德環化加成產物37 , 將化合物37照光得籠狀化合物31. 31 順丁烯二酐 ,2對苯錕 ,1,4奈錕做狄爾斯-亞德反應得單一產物為endo-anti型式與乙炔二甲酸二甲酯做狄爾斯-亞德反應得π 面選擇比為85:15,其中85%為anti型式,15% 為syn型式. 31再與氫氧化鈉,甲醇鈉鹽做處促化重排反應,與氫氧化鈉反應得重排產物 73和74,與甲醇鈉鹽反應則只得產物74. Chou,D.T. 周德璋 1993 學位論文 ; thesis 0 zh-TW
collection	NDLTD
language	zh-TW
format	Others
sources	NDLTD
description	碩士 === 東海大學 === 應用化學系 === 81 === 15,15 - 二甲基-1,12,13,14-四氯六環 [10.2.1.0(2,11) .0(4,9) (4,14) .0(9,13)]十五烷-5,7-二烯-3,10-二酮46的合成 , 係利用 3,4-四氯-5,5-二甲氧環戊二烯與1,4奈錕反應做狄爾斯-亞德環化加成產物37 , 將化合物37照光得籠狀化合物31. 31 順丁烯二酐 ,2對苯錕 ,1,4奈錕做狄爾斯-亞德反應得單一產物為endo-anti型式與乙炔二甲酸二甲酯做狄爾斯-亞德反應得π 面選擇比為85:15,其中85%為anti型式,15% 為syn型式. 31再與氫氧化鈉,甲醇鈉鹽做處促化重排反應,與氫氧化鈉反應得重排產物 73和74,與甲醇鈉鹽反應則只得產物74.
author2	Chou,D.T.
author_facet	Chou,D.T. Wu,Y.F. 吳炎豐
author	Wu,Y.F. 吳炎豐
spellingShingle	Wu,Y.F. 吳炎豐 A pentacycloundecadione ring fused cyclohexadiene: Synthesis,. pi.-facial selectivity in the Diels-Alder cyclo- addition and base-promoted rearrangements
author_sort	Wu,Y.F.
title	A pentacycloundecadione ring fused cyclohexadiene: Synthesis,. pi.-facial selectivity in the Diels-Alder cyclo- addition and base-promoted rearrangements
title_short	A pentacycloundecadione ring fused cyclohexadiene: Synthesis,. pi.-facial selectivity in the Diels-Alder cyclo- addition and base-promoted rearrangements
title_full	A pentacycloundecadione ring fused cyclohexadiene: Synthesis,. pi.-facial selectivity in the Diels-Alder cyclo- addition and base-promoted rearrangements
title_fullStr	A pentacycloundecadione ring fused cyclohexadiene: Synthesis,. pi.-facial selectivity in the Diels-Alder cyclo- addition and base-promoted rearrangements
title_full_unstemmed	A pentacycloundecadione ring fused cyclohexadiene: Synthesis,. pi.-facial selectivity in the Diels-Alder cyclo- addition and base-promoted rearrangements
title_sort	pentacycloundecadione ring fused cyclohexadiene: synthesis,. pi.-facial selectivity in the diels-alder cyclo- addition and base-promoted rearrangements
publishDate	1993
url	http://ndltd.ncl.edu.tw/handle/92946707589176539880
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A pentacycloundecadione ring fused cyclohexadiene: Synthesis,. pi.-facial selectivity in the Diels-Alder cyclo- addition and base-promoted rearrangements

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