Addition of organic moiety attecting the fates of high water solubility organic contaminants in soil

碩士 === 國立中央大學 === 環境工程研究所 === 82 === the fates of carbanates and diuron were studied in a nona- cclimated sandy loam soil spiked with various organic compoun- ds. The results showed that aerobic biodegradation of pestici- des residues by in...

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Bibliographic Details
Main Authors: Jiann-Luen Kao, 高健倫
Other Authors: J.F. Lee
Format: Others
Language:zh-TW
Published: 1994
Online Access:http://ndltd.ncl.edu.tw/handle/32165009407905059042
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Summary:碩士 === 國立中央大學 === 環境工程研究所 === 82 === the fates of carbanates and diuron were studied in a nona- cclimated sandy loam soil spiked with various organic compoun- ds. The results showed that aerobic biodegradation of pestici- des residues by indigenous microbes in soil was related to the chemical structure of the contaminants. In the experiment of migratibility in soil,the result demonstrated that the additi- on of xenobiotic organic compounds could enhance the persiste- nce of high water soluable organic contaminants in soil. The increase of xenobiotic organic compounds resulted in the incr- easing of the persistence of pesticides in aoil. The mechanism of bonding carbamate in saturated soil was elucidated from its behavior of partitioning which has reference to the water sol- ubility of the organic contaminants. The magnitude of permeab- ility from soil is releated to and govenered by the degree of water solubility of pesticides. Most of carbamates were eluted from the column of sandy loam soil wuth in 10 days.On the oth- er , the phenolic compounds added occurred oxidative-coulping reaction with SOMs and apparently remained carbamates and diu- ron in soil that resulted is decrease of migratibility of the- se contaminants.