| Summary: | 碩士 === 國立中山大學 === 化學學系 === 83 === Organoiron complexes are readily available and can serve
as starting meterials for the synthesis of numerous
natural products. The synthetic applications of the
tricarbonyliron triene complexes not been explored previously.
The organic compound, 1-methylene-4-methoxycyclohex-2,4-
diene, does not exist which will tautomerized
rapidly to 4-methylanisole. The Fe(CO)3 act as a
protecting and stabilizing group for the exocyclic
methylene group and this has important synthetic applications.
We now proposed to carry out new chemical and
stereochemistry applications of a new series of organoiron
complex. (1) Electrophilic substitution reaction ,
including trapping with nucleophiles. (2) 1,3-Dipolar
cycloaddition reactions.
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