Kinetics of Synthesis of Silicon Carbide through Carbothermal Reduction of Silicon Oxide
碩士 === 國立台灣工業技術學院 === 化學工程技術研究所 === 85 === The kinetics of synthesis of silicon carbide through carbothermal reduction of silicon dioxide has been studied in our experiment. X-ray diffraction analysis were employed to determine the...
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ndltd-TW-085NTUST0620362016-07-01T04:15:47Z http://ndltd.ncl.edu.tw/handle/94220456840643778964 Kinetics of Synthesis of Silicon Carbide through Carbothermal Reduction of Silicon Oxide 碳熱還原二氧化矽製備碳化矽之動力學研究 Chen, Chih-yung 陳智勇 碩士 國立台灣工業技術學院 化學工程技術研究所 85 The kinetics of synthesis of silicon carbide through carbothermal reduction of silicon dioxide has been studied in our experiment. X-ray diffraction analysis were employed to determine the content of products. The effects of several parameters on the reaction rate were obtained. Experimental results indicated that the reaction rate could be increased by decreasing the flow rate of He, the SiO2/C ratio, the grain size of silicon oxide or carbon and the initial density of solid sample. The rate could also be increased by increasing the height of solid sample and the reaction temperature. It was also found implicitly that SiO was an intermediate product. The activation energy of the production of β-SiC was found to be 436kJ/mole. Following are the empirical rate expressions of conversions of carbon, silicon oxide and production of silicon carbide obtained by regression of the experimental data: dCc-rc = - -------- = 7.6E4 *exp(-412,132/RT) *dsio2^(-0.742)* dc^(-0.549) dt *Csio2^(0.308)* Cc^(0.316)*Csic^(-0.046)*D^(-0.218) *f^(-0.311)*h^(0.460) dCc-rsio2 = - ------ = 1.2E4 *exp(-401,513/RT) *dsio2^(-0.801)*dc^(-0.392) dt *Csio2^(0.476)*Cc^(0.283)*Csic^(-0.077)*D^(-0.241) *f^(-0.304)*h^(0.412) dCsicrsic = -------- = 2.5E4 *exp(-436,012/RT) *dsio2^(-0.474)*dc^(-0.315) dt *Csio2^(0.407)*Cc^(0.328)*Csic^(0.013)*D^(-0.234) *f^(-0.352)*h^(0.414) The applicable range of the empirical rate expressions are flow rate of He 1x10-5 - 5x10-5 m3/s, sample height 0.007 - 0.020m, reaction temperature 1,573 - 1,773K, SiO2/C molar ratio 1/5 - 1/1, grain size of silicon oxide 0.000042 - 0.000113m, grain size of carbon 0.000051 - 0.000134m and initial bulk density 339.5 - 577.2kg/m3. Lin Chun-I 林俊一 1997 學位論文 ; thesis 127 zh-TW |
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碩士 === 國立台灣工業技術學院 === 化學工程技術研究所 === 85 === The kinetics of synthesis of silicon carbide through
carbothermal reduction of silicon dioxide has been studied in
our experiment. X-ray diffraction analysis were employed to
determine the content of products. The effects of several
parameters on the reaction rate were obtained. Experimental
results indicated that the reaction rate could be increased by
decreasing the flow rate of He, the SiO2/C ratio, the grain size
of silicon oxide or carbon and the initial density of solid
sample. The rate could also be increased by increasing the
height of solid sample and the reaction temperature. It was
also found implicitly that SiO was an intermediate product. The
activation energy of the production of β-SiC was found to be
436kJ/mole. Following are the empirical rate expressions of
conversions of carbon, silicon oxide and production of silicon
carbide obtained by regression of the experimental data:
dCc-rc = - -------- = 7.6E4 *exp(-412,132/RT) *dsio2^(-0.742)*
dc^(-0.549) dt *Csio2^(0.308)*
Cc^(0.316)*Csic^(-0.046)*D^(-0.218)
*f^(-0.311)*h^(0.460) dCc-rsio2 = - ------ = 1.2E4
*exp(-401,513/RT) *dsio2^(-0.801)*dc^(-0.392) dt
*Csio2^(0.476)*Cc^(0.283)*Csic^(-0.077)*D^(-0.241)
*f^(-0.304)*h^(0.412) dCsicrsic = -------- = 2.5E4
*exp(-436,012/RT) *dsio2^(-0.474)*dc^(-0.315) dt
*Csio2^(0.407)*Cc^(0.328)*Csic^(0.013)*D^(-0.234)
*f^(-0.352)*h^(0.414) The applicable range of the
empirical rate expressions are flow rate of He 1x10-5 - 5x10-5
m3/s, sample height 0.007 - 0.020m, reaction temperature 1,573 -
1,773K, SiO2/C molar ratio 1/5 - 1/1, grain size of silicon
oxide 0.000042 - 0.000113m, grain size of carbon 0.000051 -
0.000134m and initial bulk density 339.5 - 577.2kg/m3.
|
author2 |
Lin Chun-I |
author_facet |
Lin Chun-I Chen, Chih-yung 陳智勇 |
author |
Chen, Chih-yung 陳智勇 |
spellingShingle |
Chen, Chih-yung 陳智勇 Kinetics of Synthesis of Silicon Carbide through Carbothermal Reduction of Silicon Oxide |
author_sort |
Chen, Chih-yung |
title |
Kinetics of Synthesis of Silicon Carbide through Carbothermal Reduction of Silicon Oxide |
title_short |
Kinetics of Synthesis of Silicon Carbide through Carbothermal Reduction of Silicon Oxide |
title_full |
Kinetics of Synthesis of Silicon Carbide through Carbothermal Reduction of Silicon Oxide |
title_fullStr |
Kinetics of Synthesis of Silicon Carbide through Carbothermal Reduction of Silicon Oxide |
title_full_unstemmed |
Kinetics of Synthesis of Silicon Carbide through Carbothermal Reduction of Silicon Oxide |
title_sort |
kinetics of synthesis of silicon carbide through carbothermal reduction of silicon oxide |
publishDate |
1997 |
url |
http://ndltd.ncl.edu.tw/handle/94220456840643778964 |
work_keys_str_mv |
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