Shrinking Characteristics, Internal Pigmentability and Mechanical Properties of Low-Shrink Unsaturated Polyester Resins: Effect of the Structure and Molecular Weight of Polyurethane-based Low Profile

碩士 === 國立台灣工業技術學院 === 化學工程技術研究所 === 85 === The effect of five thermoplastic polyurethane(PU)-based low profile additives(LPA) with different chemical structure and molecular weight on the volume shrinkage chacteristics, internal pigmentabil...

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Bibliographic Details
Main Authors: Dong, Ji-ping, 董志平
Other Authors: Yi-Hsu Ju, C.J. Liu
Format: Others
Language:zh-TW
Published: 1997
Online Access:http://ndltd.ncl.edu.tw/handle/63624109966625969497
Description
Summary:碩士 === 國立台灣工業技術學院 === 化學工程技術研究所 === 85 === The effect of five thermoplastic polyurethane(PU)-based low profile additives(LPA) with different chemical structure and molecular weight on the volume shrinkage chacteristics, internal pigmentability and mechanical properties for three low-chrink unsaturated polyester resin(UP) based on maleic anhydride(MA)- propylene glycol(PG), MA-PG-PA(phthalic anhydride), and MA-PG- IPA(isophthalic acid) types of UP respectively after the cure were investigated. The experimental results have been explained by phase chactistics of the ternary styrene/UP/LPA, reaction conversion, cured sample morphology, volume fraction of microvoid, and the composition change in the continuous crosslinked polyester phase as a result of phase separation during the cure.