Summary: | 碩士 === 國立中央大學 === 化學工程學系 === 86 === In this study ,waste foaming polystyrene is used for raw
material .The nitration reaction proceeds to use the mixed
nitric acid and sulfuric acid ,then use the mixed acid to
control the degree of the nitration.The NPS is reduced to use
the phenyl-hydrazine to get the Amino-polystyrene(AMPS),then
amino-polystyrene after sulfonation gets the Amino-polystyrene
sulfonic acid(SA-PSSA),or NPS after sulfonation gets the nitro-
polystyrene sulfonic acid (NPS-PSSA),the NPS-PSSA is reduced to
use the phenylhydrazine to get the amino-polystyrene-polystyrnen
sulfonic acid.It can get the polymer-azo-dye by diazotiation
coupling with N-1-Naphthylethyldiamine Dihydrochloride(NEDA),and
compared the UV spectrum to sulfanilamide,orthanilic acid,p-
toluidine,aniline with the analogous structure.
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