PPO/PA66 blending and characterization of reactive interface compatibilization

碩士 === 淡江大學 === 化學工程學系研究所 === 86 === This research places emphasis upon the in-site compatibilization reaction of PPO and PA66 in a blending formation process. The addition of appropriate multi-functional molecules, MAH and styrene, that were preformed graftor block...

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Bibliographic Details
Main Authors: Ou, Tzong-Her, 歐宗和
Other Authors: Dar-Long Lin
Format: Others
Language:zh-TW
Published: 1998
Online Access:http://ndltd.ncl.edu.tw/handle/17116743607055989578
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Summary:碩士 === 淡江大學 === 化學工程學系研究所 === 86 === This research places emphasis upon the in-site compatibilization reaction of PPO and PA66 in a blending formation process. The addition of appropriate multi-functional molecules, MAH and styrene, that were preformed graftor block copolymers by free radical reaction to act as interfacial agents.First MAH and styrene were graft onto the main or ends of PPO to forman oligomeric chain of poly(MAH-co-styrene). Subsequently, the anhydridegroup of MAH was reacted with the terminal amino group of PA66.In this case,FTIR spectrometry analysis in dicated an high quantity of interfacial chainlinkage between these polymers.I mprovement of compatibility between PPO andPA66 wereevidence from WAXS, DSC,D MA, rheometric analysis and SEM.