Kinetic Study of the Reactions of M(CO)6 ( M = Cr、Mo、W ) in Cyclohexane using Laser Photolysis-Time-Resolved Fourier Transform Infrared Spectroscopy

Kinetic Study of the Reactions of M(CO)6 ( M = Cr、Mo、W ) in Cyclohexane using Laser Photolysis-Time-Resolved Fourier Transform Infrared Spectroscopy

碩士 === 國立交通大學 === 應用化學系 === 87 === Tne kinetics of the reactions of M(CO)6 ( M = Cr、Mo、W ) with ligands ( (CH3)2CO、C6H6、H2O ) in cyclohexane were studied using laser photolysis-time-resolved Fourier transform infrared spectroscopy technique. We have assigned the absorption...

Full description

Bibliographic Details
Main Authors: Ta Wen Liao, 廖達文
Other Authors: Niann S. Wang
Format: Others
Language:zh-TW
Published: 1999
Online Access:http://ndltd.ncl.edu.tw/handle/30894657548297443372
id ndltd-TW-087NCTU0500057
record_format oai_dc
spelling ndltd-TW-087NCTU05000572016-07-11T04:13:50Z http://ndltd.ncl.edu.tw/handle/30894657548297443372 Kinetic Study of the Reactions of M(CO)6 ( M = Cr、Mo、W ) in Cyclohexane using Laser Photolysis-Time-Resolved Fourier Transform Infrared Spectroscopy 利用雷射光解-時域解析-霍氏轉換紅外光譜法研究六羰基金屬(鉻、鉬、鎢)在環己烷溶液中之反應動力學 Ta Wen Liao 廖達文 碩士 國立交通大學 應用化學系 87 Tne kinetics of the reactions of M(CO)6 ( M = Cr、Mo、W ) with ligands ( (CH3)2CO、C6H6、H2O ) in cyclohexane were studied using laser photolysis-time-resolved Fourier transform infrared spectroscopy technique. We have assigned the absorption positions of transient species M(CO)5S ( S = cyclo-C6H12 ) and M(CO)5L ( L = (CH3)2CO、C6H6、H2O ) and determined the absolute rate coefficients for the reactions of M(CO)5S with ligands. Our results were compared with previous studies. Niann S. Wang 王念夏 1999 學位論文 ; thesis 77 zh-TW
collection NDLTD
language zh-TW
format Others
sources NDLTD
description 碩士 === 國立交通大學 === 應用化學系 === 87 === Tne kinetics of the reactions of M(CO)6 ( M = Cr、Mo、W ) with ligands ( (CH3)2CO、C6H6、H2O ) in cyclohexane were studied using laser photolysis-time-resolved Fourier transform infrared spectroscopy technique. We have assigned the absorption positions of transient species M(CO)5S ( S = cyclo-C6H12 ) and M(CO)5L ( L = (CH3)2CO、C6H6、H2O ) and determined the absolute rate coefficients for the reactions of M(CO)5S with ligands. Our results were compared with previous studies.
author2 Niann S. Wang
author_facet Niann S. Wang
Ta Wen Liao
廖達文
author Ta Wen Liao
廖達文
spellingShingle Ta Wen Liao
廖達文
Kinetic Study of the Reactions of M(CO)6 ( M = Cr、Mo、W ) in Cyclohexane using Laser Photolysis-Time-Resolved Fourier Transform Infrared Spectroscopy
author_sort Ta Wen Liao
title Kinetic Study of the Reactions of M(CO)6 ( M = Cr、Mo、W ) in Cyclohexane using Laser Photolysis-Time-Resolved Fourier Transform Infrared Spectroscopy
title_short Kinetic Study of the Reactions of M(CO)6 ( M = Cr、Mo、W ) in Cyclohexane using Laser Photolysis-Time-Resolved Fourier Transform Infrared Spectroscopy
title_full Kinetic Study of the Reactions of M(CO)6 ( M = Cr、Mo、W ) in Cyclohexane using Laser Photolysis-Time-Resolved Fourier Transform Infrared Spectroscopy
title_fullStr Kinetic Study of the Reactions of M(CO)6 ( M = Cr、Mo、W ) in Cyclohexane using Laser Photolysis-Time-Resolved Fourier Transform Infrared Spectroscopy
title_full_unstemmed Kinetic Study of the Reactions of M(CO)6 ( M = Cr、Mo、W ) in Cyclohexane using Laser Photolysis-Time-Resolved Fourier Transform Infrared Spectroscopy
title_sort kinetic study of the reactions of m(co)6 ( m = cr、mo、w ) in cyclohexane using laser photolysis-time-resolved fourier transform infrared spectroscopy
publishDate 1999
url http://ndltd.ncl.edu.tw/handle/30894657548297443372
work_keys_str_mv AT tawenliao kineticstudyofthereactionsofmco6mcrmowincyclohexaneusinglaserphotolysistimeresolvedfouriertransforminfraredspectroscopy
AT liàodáwén kineticstudyofthereactionsofmco6mcrmowincyclohexaneusinglaserphotolysistimeresolvedfouriertransforminfraredspectroscopy
AT tawenliao lìyòngléishèguāngjiěshíyùjiěxīhuòshìzhuǎnhuànhóngwàiguāngpǔfǎyánjiūliùtāngjījīnshǔluòmùwūzàihuánjǐwánróngyèzhōngzhīfǎnyīngdònglìxué
AT liàodáwén lìyòngléishèguāngjiěshíyùjiěxīhuòshìzhuǎnhuànhóngwàiguāngpǔfǎyánjiūliùtāngjījīnshǔluòmùwūzàihuánjǐwánróngyèzhōngzhīfǎnyīngdònglìxué
_version_ 1718343743294144512

Similar Items