| Summary: | 碩士 === 國立交通大學 === 材料科學與工程系 === 89 === ABSTRACT
The using of hydrogen bond to build supramolecular complexes for novel liquid crystalline materials have been widely developed recently. The complexes are built by two different constituents, one as the proton donor and the other as the proton acceptor. The ease of tuning supramolecular structures made the materials to be a potential candidate for the use in the optoelectronic devices. This research is mainly to investigate the synthesis and characterization of H-bonded side-chain liquid crystalline polymers.
Benzoic acid and stilbazole units were connected to the spacer, and then they were attached to the polymerizable group (i.e. acryloyl). The monomer/monomer, polymer/monomer, polymer/polymer complexes were studied; hence, the influence of the polymer backbone can be clearly studied. Moreover, the influence of angular bending and spacer length on physical properties are also studied and all are characterized by DSC and Powder XRD.
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