The valence-band photoemission studies of N- and B-doped diamond films

碩士 === 淡江大學 === 物理學系 === 89 === We present the photoemission study of nitrogen (N) and boron (B) containing diamond film at room temperature. Diamond films were grown on silicon (Si) substrates by the microwave plasma-enhanced chemical vapor deposition method (MPECVD). The valence-band ph...

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Bibliographic Details
Main Authors: An-Ping Chiu, 邱安平
Other Authors: Way-Faung Pong
Format: Others
Language:zh-TW
Published: 2001
Online Access:http://ndltd.ncl.edu.tw/handle/35896638768375262920
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Summary:碩士 === 淡江大學 === 物理學系 === 89 === We present the photoemission study of nitrogen (N) and boron (B) containing diamond film at room temperature. Diamond films were grown on silicon (Si) substrates by the microwave plasma-enhanced chemical vapor deposition method (MPECVD). The valence-band photoelectron spectra (PES) indicate that N and B atoms cause the broadening of the valence band π- and σ-bond features and the enhancement and reduction of the π- and σ-bond features, respectively. We also found that N- and B-doping induced partial graphitization in some small regions in the diamond films and enhanced the occupied sp3-bond states of the host atoms surrounding the N and B impurities.