Synthesis of Germanium and Lead complexes containing Diselenophosphate Ligands
碩士 === 中原大學 === 化學研究所 === 93 === Complexes (C6H5)3MSe2P(OR)2 (M=Ge, Pb;R=iPr, Et, nPr) were prepared from the reaction of (C6H5)3MCl and NH4Se2P(OR)2 in a molar ratio of 1:1 in diethyl ether at 0 °C. The complexes were characterized by elemental analysis, 1H, 31P, 77Se NMR, positive FAB mass and X-r...
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ndltd-TW-093CYCU50650052015-10-13T13:08:18Z http://ndltd.ncl.edu.tw/handle/66308009510653598507 Synthesis of Germanium and Lead complexes containing Diselenophosphate Ligands 含二硒磷酸配位基之鍺、鉛金屬錯合物的合成 Chia-Liang Hsiao 蕭价良 碩士 中原大學 化學研究所 93 Complexes (C6H5)3MSe2P(OR)2 (M=Ge, Pb;R=iPr, Et, nPr) were prepared from the reaction of (C6H5)3MCl and NH4Se2P(OR)2 in a molar ratio of 1:1 in diethyl ether at 0 °C. The complexes were characterized by elemental analysis, 1H, 31P, 77Se NMR, positive FAB mass and X-ray. The X-ray structure consists of three phenyl rings connected to metal atom and a selenium atom from diselenophosphate ligand is also coordinated to metal atom. The other selenium atom of diselenophosphate ligand is dangling. The coordination geometry around the metal atom is distorted tetrahedral. Compounds Pb[Se2P(OR)]2 (R=iPr, Et, nPr,) were prepared from the reaction of Pb(CH3COO)2•3H2O and NH4Se2P(OR)2 in a molar ratio of 1:2 in methanol at room temperature. The complexes were characterized by elemental analysis, 1H, 31P, 77Se NMR, positive FAB mass and X-ray. C. W. Liu 劉鎮維 2005 學位論文 ; thesis 106 zh-TW |
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碩士 === 中原大學 === 化學研究所 === 93 === Complexes (C6H5)3MSe2P(OR)2 (M=Ge, Pb;R=iPr, Et, nPr) were prepared from the reaction of (C6H5)3MCl and NH4Se2P(OR)2 in a molar ratio of 1:1 in diethyl ether at 0 °C. The complexes were characterized by elemental analysis, 1H, 31P, 77Se NMR, positive FAB mass and X-ray. The X-ray structure consists of three phenyl rings connected to metal atom and a selenium atom from diselenophosphate ligand is also coordinated to metal atom. The other selenium atom of diselenophosphate ligand is dangling. The coordination geometry around the metal atom is distorted tetrahedral.
Compounds Pb[Se2P(OR)]2 (R=iPr, Et, nPr,) were prepared from the reaction of Pb(CH3COO)2•3H2O and NH4Se2P(OR)2 in a molar ratio of 1:2 in methanol at room temperature. The complexes were characterized by elemental analysis, 1H, 31P, 77Se NMR, positive FAB mass and X-ray.
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author2 |
C. W. Liu |
author_facet |
C. W. Liu Chia-Liang Hsiao 蕭价良 |
author |
Chia-Liang Hsiao 蕭价良 |
spellingShingle |
Chia-Liang Hsiao 蕭价良 Synthesis of Germanium and Lead complexes containing Diselenophosphate Ligands |
author_sort |
Chia-Liang Hsiao |
title |
Synthesis of Germanium and Lead complexes containing Diselenophosphate Ligands |
title_short |
Synthesis of Germanium and Lead complexes containing Diselenophosphate Ligands |
title_full |
Synthesis of Germanium and Lead complexes containing Diselenophosphate Ligands |
title_fullStr |
Synthesis of Germanium and Lead complexes containing Diselenophosphate Ligands |
title_full_unstemmed |
Synthesis of Germanium and Lead complexes containing Diselenophosphate Ligands |
title_sort |
synthesis of germanium and lead complexes containing diselenophosphate ligands |
publishDate |
2005 |
url |
http://ndltd.ncl.edu.tw/handle/66308009510653598507 |
work_keys_str_mv |
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