Synthesis and Applications of Sulfur-substituted Indolizines and Quinolizines
碩士 === 輔仁大學 === 化學系 === 93 === This thesis mainly studied the [4+2] cycloaddition reactions of C-2 substituted 4-phenylthio-3-sulfolenes 48a and 48b with p-toluenesulfonyl isocyanate (PTSI) to yield 6-membered ring nitrogen compounds 49a and 49b. The tosyl group of 49a and 49b was then cleaved to g...
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ndltd-TW-093FJU000650062015-10-13T15:29:17Z http://ndltd.ncl.edu.tw/handle/09789084940139033076 Synthesis and Applications of Sulfur-substituted Indolizines and Quinolizines 硫取代之與衍生物的合成與應用 Ho Chung-Wen 何仲文 碩士 輔仁大學 化學系 93 This thesis mainly studied the [4+2] cycloaddition reactions of C-2 substituted 4-phenylthio-3-sulfolenes 48a and 48b with p-toluenesulfonyl isocyanate (PTSI) to yield 6-membered ring nitrogen compounds 49a and 49b. The tosyl group of 49a and 49b was then cleaved to give compounds 50a and 50b, which under basic condition underwent intramolecular cyclization to yield indolizine 52 and quinolizine 53. We have also carried out some functional group transformations of these bicylic compounds, and have studied the stereochemistry of these reactions. Shang-Shing P. Chou 周善行 2005 學位論文 ; thesis 0 zh-TW |
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碩士 === 輔仁大學 === 化學系 === 93 === This thesis mainly studied the [4+2] cycloaddition reactions of C-2 substituted 4-phenylthio-3-sulfolenes 48a and 48b with p-toluenesulfonyl isocyanate (PTSI) to yield 6-membered ring nitrogen compounds 49a and 49b. The tosyl group of 49a and 49b was then cleaved to give compounds 50a and 50b, which under basic condition underwent intramolecular cyclization to yield indolizine 52 and quinolizine 53. We have also carried out some functional group transformations of these bicylic compounds, and have studied the stereochemistry of these reactions.
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author2 |
Shang-Shing P. Chou |
author_facet |
Shang-Shing P. Chou Ho Chung-Wen 何仲文 |
author |
Ho Chung-Wen 何仲文 |
spellingShingle |
Ho Chung-Wen 何仲文 Synthesis and Applications of Sulfur-substituted Indolizines and Quinolizines |
author_sort |
Ho Chung-Wen |
title |
Synthesis and Applications of Sulfur-substituted Indolizines and Quinolizines |
title_short |
Synthesis and Applications of Sulfur-substituted Indolizines and Quinolizines |
title_full |
Synthesis and Applications of Sulfur-substituted Indolizines and Quinolizines |
title_fullStr |
Synthesis and Applications of Sulfur-substituted Indolizines and Quinolizines |
title_full_unstemmed |
Synthesis and Applications of Sulfur-substituted Indolizines and Quinolizines |
title_sort |
synthesis and applications of sulfur-substituted indolizines and quinolizines |
publishDate |
2005 |
url |
http://ndltd.ncl.edu.tw/handle/09789084940139033076 |
work_keys_str_mv |
AT hochungwen synthesisandapplicationsofsulfursubstitutedindolizinesandquinolizines AT hézhòngwén synthesisandapplicationsofsulfursubstitutedindolizinesandquinolizines AT hochungwen liúqǔdàizhīyǔyǎnshēngwùdehéchéngyǔyīngyòng AT hézhòngwén liúqǔdàizhīyǔyǎnshēngwùdehéchéngyǔyīngyòng |
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