Chemical Synthesis and Ionic Conductivity of Water-Soluble Articulated Rigid-Rod Polyelectrolytes Derivatized with Sulfonated Ionomer Pendants

Chemical Synthesis and Ionic Conductivity of Water-Soluble Articulated Rigid-Rod Polyelectrolytes Derivatized with Sulfonated Ionomer Pendants

碩士 === 國立中山大學 === 材料科學研究所 === 93 === Articulated rigid-rod polymers asPBI were synthesized via polycondensation reaction. Using 2-sulfoterephthalic acid and 5-sulfoisophthalic acid in different ratios for copolycondensation reaction making the fully conjugated rigid-rod backbone became articulated....

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Main Authors: Yue-Lin Du, 杜岳霖
Other Authors: Shih-Jung Bai
Format: Others
Language:zh-TW
Published: 2004
Online Access:http://ndltd.ncl.edu.tw/handle/50733740246668114282
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spelling ndltd-TW-093NSYS51590032015-12-23T04:08:01Z http://ndltd.ncl.edu.tw/handle/50733740246668114282 Chemical Synthesis and Ionic Conductivity of Water-Soluble Articulated Rigid-Rod Polyelectrolytes Derivatized with Sulfonated Ionomer Pendants 衍生磺酸離子懸垂基之水溶性鉸鏈型硬桿式共聚電解質的化學合成與離子導電性 Yue-Lin Du 杜岳霖 碩士 國立中山大學 材料科學研究所 93 Articulated rigid-rod polymers asPBI were synthesized via polycondensation reaction. Using 2-sulfoterephthalic acid and 5-sulfoisophthalic acid in different ratios for copolycondensation reaction making the fully conjugated rigid-rod backbone became articulated. Both rigid-rod and articulated rigid-rod were further derivatized using alkane sulfonated pendants and became water-soluble rigid-rod and articulated rigid-rod polyelectrolytes. Lithium salt doped cast films of the polyelectrolytes showed a root-temperature DC conductivity parallel to film surface ( Shih-Jung Bai 白世榮 2004 學位論文 ; thesis 174 zh-TW
collection NDLTD
language zh-TW
format Others
sources NDLTD
description 碩士 === 國立中山大學 === 材料科學研究所 === 93 === Articulated rigid-rod polymers asPBI were synthesized via polycondensation reaction. Using 2-sulfoterephthalic acid and 5-sulfoisophthalic acid in different ratios for copolycondensation reaction making the fully conjugated rigid-rod backbone became articulated. Both rigid-rod and articulated rigid-rod were further derivatized using alkane sulfonated pendants and became water-soluble rigid-rod and articulated rigid-rod polyelectrolytes. Lithium salt doped cast films of the polyelectrolytes showed a root-temperature DC conductivity parallel to film surface (
author2 Shih-Jung Bai
author_facet Shih-Jung Bai
Yue-Lin Du
杜岳霖
author Yue-Lin Du
杜岳霖
spellingShingle Yue-Lin Du
杜岳霖
Chemical Synthesis and Ionic Conductivity of Water-Soluble Articulated Rigid-Rod Polyelectrolytes Derivatized with Sulfonated Ionomer Pendants
author_sort Yue-Lin Du
title Chemical Synthesis and Ionic Conductivity of Water-Soluble Articulated Rigid-Rod Polyelectrolytes Derivatized with Sulfonated Ionomer Pendants
title_short Chemical Synthesis and Ionic Conductivity of Water-Soluble Articulated Rigid-Rod Polyelectrolytes Derivatized with Sulfonated Ionomer Pendants
title_full Chemical Synthesis and Ionic Conductivity of Water-Soluble Articulated Rigid-Rod Polyelectrolytes Derivatized with Sulfonated Ionomer Pendants
title_fullStr Chemical Synthesis and Ionic Conductivity of Water-Soluble Articulated Rigid-Rod Polyelectrolytes Derivatized with Sulfonated Ionomer Pendants
title_full_unstemmed Chemical Synthesis and Ionic Conductivity of Water-Soluble Articulated Rigid-Rod Polyelectrolytes Derivatized with Sulfonated Ionomer Pendants
title_sort chemical synthesis and ionic conductivity of water-soluble articulated rigid-rod polyelectrolytes derivatized with sulfonated ionomer pendants
publishDate 2004
url http://ndltd.ncl.edu.tw/handle/50733740246668114282
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