Preparation and Structural Analyses of Substituted Dithiahexahydro[3.3] yclophane and It’s Copper(I) and Silver(I) Complexes
碩士 === 靜宜大學 === 應用化學研究所 === 93 === Cyclophanes possess the nature of rigidity and the character of electric current the benzene rings, which are able to influence each other between two ring. A number of researchers are interesting in the nature. In this work, a series of substituted trans-dithiahex...
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| Format: | Others |
| Language: | zh-TW |
| Published: |
2005
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| Online Access: | http://ndltd.ncl.edu.tw/handle/22495090251492374429 |
| Summary: | 碩士 === 靜宜大學 === 應用化學研究所 === 93 === Cyclophanes possess the nature of rigidity and the character of electric current the benzene rings, which are able to influence each other between two ring. A number of researchers are interesting in the nature. In this work, a series of substituted trans-dithiahexahydro[3.3]paracyclo- phanes were prepared for structural study.
Under a high-dilute condition, a series of substituted
trans-dithiahexahydro[3.3]paracyclophane were prepared via a coupling reaction of the corresponding trans-1,4-bis(merca-ptomethyl)cyclohexane and substituted 1,4-bis(bromo-methyl)benzene in a 10% ethanolic NaOH solution. Substituted dithiahexahydro[3.3]paracyclophanes were characterized by using of various analytic methods.
Trans-tetrathia-dodecahydro[3.3.3.3]paracyclophane is able to form the complexes with Cu+ or Ag+ by means of two solvents with a slow diffusion process. The structures of those complexes were characterized by using x-ray diffractometer and reuealed the different bonding fashion
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