Sequential Claisen rearrangement/Baylis-Hillman reaction/ring closing metathesis from isovanillin as a new route for the synthesis of substituted cyanonaphthalenes
碩士 === 高雄醫學大學 === 醫藥暨應用化學研究所碩士班 === 94 === In this thesis, a novel route for the synthesis of substituted cyanonaphthalenes was described. The synthetic strategy was started from isovanillin and through a sequence of reactions including O-allylation、Claisen rearrangement、O-alkylation、Baylis-Hillman...
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Other Authors: | |
Format: | Others |
Language: | zh-TW |
Published: |
2006
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Online Access: | http://ndltd.ncl.edu.tw/handle/37366667358827056017 |
Summary: | 碩士 === 高雄醫學大學 === 醫藥暨應用化學研究所碩士班 === 94 === In this thesis, a novel route for the synthesis of substituted cyanonaphthalenes was described. The synthetic strategy was started from isovanillin and through a sequence of reactions including O-allylation、Claisen rearrangement、O-alkylation、Baylis-Hillman reaction, and ring-closing metathesis to produce title compounds 5-alkoxy-6-methoxynaphthalene-2-carbonitrile, in high yields.
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