7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應

碩士 === 國立清華大學 === 化學系 === 94 === The asymmetric addition of alkynylizinc to benzaldehyde were catalized by the chiral β-amino alcohol 3 derived from ketopinic acid in few stepts. When the addition of alkynylizinc to benzaldehyde was conducted at -20oC in the presence of 10 mol% catalyst, the alkynyl...

Full description

Bibliographic Details
Main Author: 陳哲嘉
Other Authors: Biing-Jian Uang
Format: Others
Language:zh-TW
Published: 2006
Online Access:http://ndltd.ncl.edu.tw/handle/02103045688289465698
id ndltd-TW-094NTHU5065069
record_format oai_dc
spelling ndltd-TW-094NTHU50650692015-12-16T04:42:34Z http://ndltd.ncl.edu.tw/handle/02103045688289465698 7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應 陳哲嘉 碩士 國立清華大學 化學系 94 The asymmetric addition of alkynylizinc to benzaldehyde were catalized by the chiral β-amino alcohol 3 derived from ketopinic acid in few stepts. When the addition of alkynylizinc to benzaldehyde was conducted at -20oC in the presence of 10 mol% catalyst, the alkynyl alcohol was obtained in 83% yield and 45% e.e. Biing-Jian Uang 汪炳鈞 2006 學位論文 ; thesis 54 zh-TW
collection NDLTD
language zh-TW
format Others
sources NDLTD
description 碩士 === 國立清華大學 === 化學系 === 94 === The asymmetric addition of alkynylizinc to benzaldehyde were catalized by the chiral β-amino alcohol 3 derived from ketopinic acid in few stepts. When the addition of alkynylizinc to benzaldehyde was conducted at -20oC in the presence of 10 mol% catalyst, the alkynyl alcohol was obtained in 83% yield and 45% e.e.
author2 Biing-Jian Uang
author_facet Biing-Jian Uang
陳哲嘉
author 陳哲嘉
spellingShingle 陳哲嘉
7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應
author_sort 陳哲嘉
title 7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應
title_short 7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應
title_full 7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應
title_fullStr 7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應
title_full_unstemmed 7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應
title_sort 7,7-dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應
publishDate 2006
url http://ndltd.ncl.edu.tw/handle/02103045688289465698
work_keys_str_mv AT chénzhéjiā 77dimethyl1morpholin4ylbicyclo221heptan2olcuīhuàguìduìquánbùduìchēngjiāchéngfǎnyīng
_version_ 1718151932078456832