7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應
碩士 === 國立清華大學 === 化學系 === 94 === The asymmetric addition of alkynylizinc to benzaldehyde were catalized by the chiral β-amino alcohol 3 derived from ketopinic acid in few stepts. When the addition of alkynylizinc to benzaldehyde was conducted at -20oC in the presence of 10 mol% catalyst, the alkynyl...
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ndltd-TW-094NTHU50650692015-12-16T04:42:34Z http://ndltd.ncl.edu.tw/handle/02103045688289465698 7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應 陳哲嘉 碩士 國立清華大學 化學系 94 The asymmetric addition of alkynylizinc to benzaldehyde were catalized by the chiral β-amino alcohol 3 derived from ketopinic acid in few stepts. When the addition of alkynylizinc to benzaldehyde was conducted at -20oC in the presence of 10 mol% catalyst, the alkynyl alcohol was obtained in 83% yield and 45% e.e. Biing-Jian Uang 汪炳鈞 2006 學位論文 ; thesis 54 zh-TW |
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zh-TW |
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Others
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碩士 === 國立清華大學 === 化學系 === 94 === The asymmetric addition of alkynylizinc to benzaldehyde were catalized by the chiral β-amino alcohol 3 derived from ketopinic acid in few stepts. When the addition of alkynylizinc to benzaldehyde was conducted at -20oC in the presence of 10 mol% catalyst, the alkynyl alcohol was obtained in 83% yield and 45% e.e.
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author2 |
Biing-Jian Uang |
author_facet |
Biing-Jian Uang 陳哲嘉 |
author |
陳哲嘉 |
spellingShingle |
陳哲嘉 7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應 |
author_sort |
陳哲嘉 |
title |
7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應 |
title_short |
7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應 |
title_full |
7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應 |
title_fullStr |
7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應 |
title_full_unstemmed |
7,7-Dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應 |
title_sort |
7,7-dimethyl-1-morpholin-4-yl-bicyclo[2.2.1]heptan-2-ol催化炔對醛不對稱加成反應 |
publishDate |
2006 |
url |
http://ndltd.ncl.edu.tw/handle/02103045688289465698 |
work_keys_str_mv |
AT chénzhéjiā 77dimethyl1morpholin4ylbicyclo221heptan2olcuīhuàguìduìquánbùduìchēngjiāchéngfǎnyīng |
_version_ |
1718151932078456832 |