Synthesis and Optoelectronic Properties of Novel Aromatic Polyamides and Polyimides Bearing Trifluoromethyl- or Methyl-Substituted Triphenylamine Moieties
碩士 === 大同大學 === 化學工程學系(所) === 94 === Two triphenylamine-containing diamine monomers, 4,4’-diamino-4”-trifluoromethyltriphenylamine and 4,4’-diamino-4”-methyltriphenylamine were synthesized via the cesium fluoride-mediated N-arylation reactions of 4-trifluoromethylaniline and p-toluidine, respectivel...
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ndltd-TW-094TTU050630072015-12-16T04:38:40Z http://ndltd.ncl.edu.tw/handle/75550263822266962096 Synthesis and Optoelectronic Properties of Novel Aromatic Polyamides and Polyimides Bearing Trifluoromethyl- or Methyl-Substituted Triphenylamine Moieties 具有三氟甲基或甲基取代之三苯胺成分的新型芳香族聚醯胺及聚醯亞胺之合成與光電性質研究 Kai-Han Lin 林楷翰 碩士 大同大學 化學工程學系(所) 94 Two triphenylamine-containing diamine monomers, 4,4’-diamino-4”-trifluoromethyltriphenylamine and 4,4’-diamino-4”-methyltriphenylamine were synthesized via the cesium fluoride-mediated N-arylation reactions of 4-trifluoromethylaniline and p-toluidine, respectively, with 1-fluoro-4-nitrobenzene, followed by palladium-catalyzed hydrazine reduction of the resulting dinitro triphenylamines. Novel aromatic polyamides and polyimides with trifluoromethyl- or methyl-substituted triphenylamine units were prepared by polycondensation reaction of these two diamine monomers with commercially available aromatic dicarboxylic acids and dianhydrides. All the polymers were amorphous in nature, as evidenced by X-ray diffractograms. Most of them were quite soluble in a variety of organic solvents and could be solution-cast into transparent, tough, and flexible films with good mechanical properties. They also showed high Tg or Ts values, good thermal stability, mechanical properties, and proper HOMO energy levels. Besides, the hole-transporting and electrochromic properties were also examined by electrochemical and spectroelectrochemical methods. Sheng-Huei Hsiao 蕭勝輝 2005 學位論文 ; thesis 58 en_US |
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碩士 === 大同大學 === 化學工程學系(所) === 94 === Two triphenylamine-containing diamine monomers, 4,4’-diamino-4”-trifluoromethyltriphenylamine and 4,4’-diamino-4”-methyltriphenylamine were synthesized via the cesium fluoride-mediated N-arylation reactions of 4-trifluoromethylaniline and p-toluidine, respectively, with 1-fluoro-4-nitrobenzene, followed by palladium-catalyzed hydrazine reduction of the resulting dinitro triphenylamines. Novel aromatic polyamides and polyimides with trifluoromethyl- or methyl-substituted triphenylamine units were prepared by polycondensation reaction of these two diamine monomers with commercially available aromatic dicarboxylic acids and dianhydrides. All the polymers were amorphous in nature, as evidenced by X-ray diffractograms. Most of them were quite soluble in a variety of organic solvents and could be solution-cast into transparent, tough, and flexible films with good mechanical properties. They also showed high Tg or Ts values, good thermal stability, mechanical properties, and proper HOMO energy levels. Besides, the hole-transporting and electrochromic properties were also examined by electrochemical and spectroelectrochemical methods.
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Sheng-Huei Hsiao |
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Sheng-Huei Hsiao Kai-Han Lin 林楷翰 |
author |
Kai-Han Lin 林楷翰 |
spellingShingle |
Kai-Han Lin 林楷翰 Synthesis and Optoelectronic Properties of Novel Aromatic Polyamides and Polyimides Bearing Trifluoromethyl- or Methyl-Substituted Triphenylamine Moieties |
author_sort |
Kai-Han Lin |
title |
Synthesis and Optoelectronic Properties of Novel Aromatic Polyamides and Polyimides Bearing Trifluoromethyl- or Methyl-Substituted Triphenylamine Moieties |
title_short |
Synthesis and Optoelectronic Properties of Novel Aromatic Polyamides and Polyimides Bearing Trifluoromethyl- or Methyl-Substituted Triphenylamine Moieties |
title_full |
Synthesis and Optoelectronic Properties of Novel Aromatic Polyamides and Polyimides Bearing Trifluoromethyl- or Methyl-Substituted Triphenylamine Moieties |
title_fullStr |
Synthesis and Optoelectronic Properties of Novel Aromatic Polyamides and Polyimides Bearing Trifluoromethyl- or Methyl-Substituted Triphenylamine Moieties |
title_full_unstemmed |
Synthesis and Optoelectronic Properties of Novel Aromatic Polyamides and Polyimides Bearing Trifluoromethyl- or Methyl-Substituted Triphenylamine Moieties |
title_sort |
synthesis and optoelectronic properties of novel aromatic polyamides and polyimides bearing trifluoromethyl- or methyl-substituted triphenylamine moieties |
publishDate |
2005 |
url |
http://ndltd.ncl.edu.tw/handle/75550263822266962096 |
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