Modification of Molecular Wire Comprising Redox-Active Biferrocenyl Spacer : Study of Electrochemistry and Photophysical Properties
碩士 === 國立中山大學 === 化學系研究所 === 95 === In attempting to modulate the electronic properties of molecular-wire Ru(II) complexes, we now describe an interesting example of X-tpy-Ru2+-tpy-(fc)2-tpy-Ru2+-tpy -X ( fc = ferrocenyl ; tpy = terpyridyl ; X=Cl, OMe, OH ) complexes comprising electronic donor or w...
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Other Authors: | |
Format: | Others |
Language: | zh-TW |
Published: |
2007
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Online Access: | http://ndltd.ncl.edu.tw/handle/53n7r7 |
Summary: | 碩士 === 國立中山大學 === 化學系研究所 === 95 === In attempting to modulate the electronic properties of molecular-wire Ru(II) complexes, we now describe an interesting example of X-tpy-Ru2+-tpy-(fc)2-tpy-Ru2+-tpy -X ( fc = ferrocenyl ; tpy = terpyridyl ; X=Cl, OMe, OH ) complexes comprising electronic donor or withdrawing group attached directly to the 4’-position of the terminal tpy moiety. The ground-state HOMO and LUMO energies were probed by electrochemical measurements and the excited-state photophysical properties were probed by absorption spectroscopy.
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