Synthesis and characterization of UV-Curable Organic-Inorganic Hybrid material

• Main Authors: Yuan-Ting Jhao, 趙元庭
• Other Authors: Keh-Ying Hsu
• Format: Others
• Language: zh-TW
• Published: 2008
• Online Access: http://ndltd.ncl.edu.tw/handle/13183087025036351288

碩士 === 中原大學 === 化學工程研究所 === 96 === Through mere mechanism of photosensitive, is it gather poly(amic acid) can fast curing favorable to the industrial use to let, and photoinitial source through gather poly(amic acid) sour one's own luminescence group in addition, extra mere photoinitiate is it assist to make only, to reach the goal of fast curing. Connect one through gathering the sour end of poly(amic acid), to form it with the oligomer of the ending of the acrylate group and extra to join different types of monomer(contain acrylate group), React through the above -mentioned mere ptotosensitization make system appear free radical polymerization let acrylate group form network. The connection of Acrylae group and poly(amic acid) are to react and produce through sol-gel of silane, and it is dense that silane one - OH group has the very good adhesion to the metal substrate. Monomer added is helpful too to the adhesive. Learn in the experiment, change the thickness of coating to certain extent and add different types of acrylate monomer Will influence the curing speed, the hardness and adhesive after curing, the monomer selected for use have a result most with BPA10EODA.