Synthesis and Related Reactions of Ruthenium Vinylidene Complexes with Benzophenone Imine Ligand
碩士 === 大同大學 === 化學工程學系(所) === 96 === The complex [TpRuCl(PPh3)(L)] (L=PPh3, HN=CPh2, Tp= hydrotris(pyrazolyl)borate) reacts with terminal alkynes in MeOH yield cationic vinylidene complexs [TpRu=C=CHR(PPh3)(L)+] [Cl-]. When R= HC≡CSiMe3, the vinylidene derivative react further with MeOH furnishing t...
| Main Authors: | , |
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| Other Authors: | |
| Format: | Others |
| Language: | zh-TW |
| Published: |
2008
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| Online Access: | http://ndltd.ncl.edu.tw/handle/16448561592999813838 |