Reactivity and Chemical Property of Fullerenes and Ruthenium complex
碩士 === 國立交通大學 === 應用化學研究所 === 98 === This thesis, divided in two parts, presents synthetic work of novel electron accepting materials based on fullerenes that contain chalcogenophenes for organic solar cells and designs a new type of ruthenium complex and then synthesis. For the synthesis of nove...
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ndltd-TW-098NCTU55000702016-04-18T04:21:47Z http://ndltd.ncl.edu.tw/handle/87517558987381124963 Reactivity and Chemical Property of Fullerenes and Ruthenium complex 碳簇與釕金屬化合物之反應與性質探討 Huang, Wei-Je 黃煒哲 碩士 國立交通大學 應用化學研究所 98 This thesis, divided in two parts, presents synthetic work of novel electron accepting materials based on fullerenes that contain chalcogenophenes for organic solar cells and designs a new type of ruthenium complex and then synthesis. For the synthesis of novel electron accepting materials, we use several ways to make novel electron accepting materials. First, we alkynes to react with phosphines and afford [60]fullerene derivatives. Second, we synthesized open-cage fullerences by organic reactions, so-called “molecular surgery” methods. Third, we made of cyclopropanated fullerenes through Bamford-Stevens reaction, as that of preparing PCBM. Fourth, we prepared compounds with electron-rich and electron-withdrawing groups. Fortunately, we modified the phenyl group of PCBM with furyl moiety and found that its power conversion efficiency can be as high as 3.11 % while fabricated with polymer P3HT. For dye-sensitized solar cell materials, designed and synthesized of a new type of ruthenium complexs with pyridine-pyrrole-pyridine ancillary ligands. Chuang, Shih-Ching 莊士卿 2010 學位論文 ; thesis 116 zh-TW |
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碩士 === 國立交通大學 === 應用化學研究所 === 98 === This thesis, divided in two parts, presents synthetic work of novel electron accepting materials based on fullerenes that contain chalcogenophenes for organic solar cells and designs a new type of ruthenium complex and then synthesis.
For the synthesis of novel electron accepting materials, we use several ways to make novel electron accepting materials. First, we alkynes to react with phosphines and afford [60]fullerene derivatives. Second, we synthesized open-cage fullerences by organic reactions, so-called “molecular surgery” methods. Third, we made of cyclopropanated fullerenes through Bamford-Stevens reaction, as that of preparing PCBM. Fourth, we prepared compounds with electron-rich and electron-withdrawing groups. Fortunately, we modified the phenyl group of PCBM with furyl moiety and found that its power conversion efficiency can be as high as 3.11 % while fabricated with polymer P3HT.
For dye-sensitized solar cell materials, designed and synthesized of a new type of ruthenium complexs with pyridine-pyrrole-pyridine ancillary ligands.
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author2 |
Chuang, Shih-Ching |
author_facet |
Chuang, Shih-Ching Huang, Wei-Je 黃煒哲 |
author |
Huang, Wei-Je 黃煒哲 |
spellingShingle |
Huang, Wei-Je 黃煒哲 Reactivity and Chemical Property of Fullerenes and Ruthenium complex |
author_sort |
Huang, Wei-Je |
title |
Reactivity and Chemical Property of Fullerenes and Ruthenium complex |
title_short |
Reactivity and Chemical Property of Fullerenes and Ruthenium complex |
title_full |
Reactivity and Chemical Property of Fullerenes and Ruthenium complex |
title_fullStr |
Reactivity and Chemical Property of Fullerenes and Ruthenium complex |
title_full_unstemmed |
Reactivity and Chemical Property of Fullerenes and Ruthenium complex |
title_sort |
reactivity and chemical property of fullerenes and ruthenium complex |
publishDate |
2010 |
url |
http://ndltd.ncl.edu.tw/handle/87517558987381124963 |
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