| Summary: | 碩士 === 國立臺灣師範大學 === 化學系 === 98 === Se─Fe─Cu─polymer system
When [SeFe3(CO)9Cu2(MeCN)2]‡ was treated with different dipyridyl ligands, polymers [SeFe3(CO)9Cu2(tmdpy)2]n (1a), [SeFe3(CO)9Cu2- (H2bpe)2.5]n (2a), [SeFe3(CO)9Cu2(H2bpe)]n (2b), [SeFe3(CO)9Cu2(dpy)3]n (3a), [SeFe3(CO)9Cu2(dpy)1.5(MeCN)]n (3b), [{Cu(bpe)(MeCN)2}{SeFe3(CO)9- Cu(bpe)}(MeCN)]n (4a), [{Cu(bpe)(MeCN)}{SeFe3(CO)9Cu(bpe)0.5}]n (4b), and complexe [{SeFe3(CO)9}2Cu4(bpe)5(MeCN)2• MeCN] (4c) were obtained, respectively. Furthermore, the formation, nature, photophysical properties, and conductivity of polymers were discussed and elucidated on the basis of DFT calculations.
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