主族(S,Se)三鐵羰基化合物與含Cu(I)及含dipyridine試劑之合成暨電化學、電子吸收光譜、導電度與理論計算探討

• Main Author: 李育緯
• Other Authors: 謝明惠
• Format: Others
• Language: zh-TW
• Published: 2010
• Online Access: http://ndltd.ncl.edu.tw/handle/14279057650733119338

碩士 === 國立臺灣師範大學 === 化學系 === 98 === Se─Fe─Cu─polymer system When [SeFe3(CO)9Cu2(MeCN)2]‡ was treated with different dipyridyl ligands, polymers [SeFe3(CO)9Cu2(tmdpy)2]n (1a), [SeFe3(CO)9Cu2- (H2bpe)2.5]n (2a), [SeFe3(CO)9Cu2(H2bpe)]n (2b), [SeFe3(CO)9Cu2(dpy)3]n (3a), [SeFe3(CO)9Cu2(dpy)1.5(MeCN)]n (3b), [{Cu(bpe)(MeCN)2}{SeFe3(CO)9- Cu(bpe)}(MeCN)]n (4a), [{Cu(bpe)(MeCN)}{SeFe3(CO)9Cu(bpe)0.5}]n (4b), and complexe [{SeFe3(CO)9}2Cu4(bpe)5(MeCN)2• MeCN] (4c) were obtained, respectively. Furthermore, the formation, nature, photophysical properties, and conductivity of polymers were discussed and elucidated on the basis of DFT calculations.