Supramolecules of Triphenylmethyl and Pyridine Derivatives : Synthesis and Study

• Main Authors: Wun-long Wan, 萬雯龍
• Other Authors: Long-Li Lai
• Format: Others
• Language: zh-TW
• Published: 2012
• Online Access: http://ndltd.ncl.edu.tw/handle/57789419812527978866

碩士 === 國立暨南國際大學 === 應用化學系 === 101 === This thesis reports the synthesis of organic supramolecular compounds together with organic ligands, design for metal-organic framework. One contains the derivative of Boc-G1-Cl, and the other compounds contains the pyridine ring derivative. In organic supramolecular, we use triphenylmethyl chloride to synthesize compound 1,4,6-TP-1,3-NH2-Ph and compound 4,6-TP-1,3-OH-Ph. Their supramolecular structures by the non-covalent bonding interaction together with the carbon dioxide adsorption were studied. The pyridine derivatives, compound di-P3-NCO-Ph and compound H2DBA-2AMP, were allowed to react with metal and two supramolecules were formed by self-assembly, respectively. Their structures were investigated by single crystal structure determination. Keywords : metal-organic framework, supramolecular self-assembly, crystal structure.